78719 20200113145616.0 doi 10.1016/j.jct.2018.03.021 sideral 105277 ART-2018-105277 eng (orcid)0000-0001-6182-2196 Martínez-López, J.F. Universidad de Zaragoza Thermophysical and volumetric study of mixtures {p-cymene¿+¿propan-1-ol} at several temperatures and atmospheric pressure. Modeling with COSMO-RS 2018 Access copy available to the general public Unrestricted Experimental isobaric molar heat capacities at atmospheric pressure have been determined for the mixture {p-cymene + propan-1-ol} every 10 K in the temperature interval (298.8–328.5) K and over the entire composition range with a Calvet type calorimeter. Densities, necessary for calculating heat capacities, have been also measured in similar conditions. Excess molar volumes have been calculated from densities. They are positive at (318.15 and 328.15) K and sigmoidal at (298.15 and 308.15) K with negative values in the zone very rich in propan-1-ol. Excess molar heat capacities have been calculated from the molar heat capacities and show positive values. Both excess molar properties increase as the temperature rises at a given molar fraction. Excess properties are discussed in terms of intermolecular interactions. The solvation model COSMO-RS has been applied to predict the excess molar heat capacities, being the quantitative predictions rather poor. info:eu-repo/grantAgreement/ES/DGA-FSE/E52 info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-64049-C3-2-R info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 2.29 2018 THERMODYNAMICS 19 / 60 = 0.317 2018 Q2 T1 CHEMISTRY, PHYSICAL 82 / 148 = 0.554 2018 Q3 T2 0.803 2018 Atomic and Molecular Physics, and Optics 2018 Q1 Physical and Theoretical Chemistry 2018 Q1 Materials Science (miscellaneous) 2018 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Pardo, J.I. Liu, S. (orcid)0000-0001-9379-8047 Mainar, A.M. Universidad de Zaragoza 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 123 (2018), 1-7 J. Chem. Thermodyn. Journal of Chemical Thermodynamics 0021-9614 299465 http://zaguan.unizar.es/record/78719/files/texto_completo.pdf Postprint 75619 http://zaguan.unizar.es/record/78719/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:78719 articulos driver 2020-01-13-14:53:26 ARTICLE