000079108 001__ 79108
000079108 005__ 20201009175922.0
000079108 0247_ $$2doi$$a10.1016/j.poly.2016.05.040
000079108 0248_ $$2sideral$$a97475
000079108 037__ $$aART-2016-97475
000079108 041__ $$aeng
000079108 100__ $$aGiardina-Papa, Daniela
000079108 245__ $$aSynthesis and reactivity of phosphanido bridged 1, 1'-bis(diphenylphosphino)ferrocene complexes [(RF)2Pt(µ-PPh2)2M(dppf)] [M = Pt, Pd]
000079108 260__ $$c2016
000079108 5060_ $$aAccess copy available to the general public$$fUnrestricted
000079108 5203_ $$aHetero-trinuclear complexes of formula (C6F5)2Pt(µ-PPh2)2M(dppf)] dppf = 1, 1'-bis(diphenylphosphino)ferrocene, M = Pt (1), M = Pd (2)] were prepared by coupling between cis-(C6F5)2Pt(PPh2)2]Li2 and cis-MCl2(dppf). Reaction of the Pt/Pt/Fe species 1 with Ag(OClO3)(PPh3)] or I2 resulted in the formation of the complexes (C6F5)(PPh3)Pt(µ-PPh2)2Pt(dppf)] (3) and (C6F5)(I)Pt(µ-PPh2)2Pt(dppf)] (4), respectively, in which one of the pentafluorophenyl ligands has been replaced by PPh3 or I. Reaction of the Pt/Pd/Fe species 2 with Ag(ClO4) afforded the tetranuclear complex (C6F5)2Pt(µ-PPh2)2Pd(dppf)Ag] (5) where the silver atom is bonded to Pd, to one of the bridging P and to one of the dppf P atoms. With Ag(OClO3)(PPh3)], complex 5 is also formed, although mixed with Ag(PPh3)2]ClO4]. A dynamic process in solution, in which the silver atom passes from one Pd–µPPh2 bond to the other, has been observed at room temperature for complex 5. The crystal structures of 3, 4 and 5 are reported.
000079108 536__ $$9info:eu-repo/grantAgreement/ES/UZ-IBERCAJA-CAI/CB28-07$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67461-P$$9info:eu-repo/grantAgreement/ES/DGA/E21
000079108 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000079108 590__ $$a1.926$$b2016
000079108 591__ $$aCRYSTALLOGRAPHY$$b13 / 26 = 0.5$$c2016$$dQ2$$eT2
000079108 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b22 / 46 = 0.478$$c2016$$dQ2$$eT2
000079108 592__ $$a0.482$$b2016
000079108 593__ $$aMaterials Chemistry$$c2016$$dQ2
000079108 593__ $$aPhysical and Theoretical Chemistry$$c2016$$dQ3
000079108 593__ $$aInorganic Chemistry$$c2016$$dQ3
000079108 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000079108 700__ $$0(orcid)0000-0002-5881-9698$$aAra, Irene$$uUniversidad de Zaragoza
000079108 700__ $$aIbáñez, Susana
000079108 700__ $$aMastrorilli, Piero
000079108 700__ $$aGallo, Vito.
000079108 700__ $$0(orcid)0000-0003-1374-5880$$aForniés, Juan$$uUniversidad de Zaragoza
000079108 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000079108 773__ $$g120 (2016), 44-53 [39 pp.]$$pPolyhedron$$tPOLYHEDRON$$x0277-5387
000079108 8564_ $$s648348$$uhttps://zaguan.unizar.es/record/79108/files/texto_completo.pdf$$yPostprint
000079108 8564_ $$s42332$$uhttps://zaguan.unizar.es/record/79108/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000079108 909CO $$ooai:zaguan.unizar.es:79108$$particulos$$pdriver
000079108 951__ $$a2020-10-09-17:46:33
000079108 980__ $$aARTICLE