000079327 001__ 79327
000079327 005__ 20231127095530.0
000079327 0247_ $$2doi$$a10.1002/ejic.201701256
000079327 0248_ $$2sideral$$a107110
000079327 037__ $$aART-2018-107110
000079327 041__ $$aeng
000079327 100__ $$0(orcid)0000-0002-8648-2586$$aBlanco, M.C.
000079327 245__ $$aGold(I), Phosphanes, and Alkynyls: The Perfect Allies in the Search for Luminescent Compounds
000079327 260__ $$c2018
000079327 5060_ $$aAccess copy available to the general public$$fUnrestricted
000079327 5203_ $$aA family of mixed phosphane/alkynyl gold(I) complexes was prepared by addition of PPh3 or PPh2py to suspensions of the polymeric species [Au(C=CR)n] [R = Ph, 2-pyridyl (py)] and [Au2{C=C(CH2)3C=C}]n. The resulting complexes are luminescent both at room and low temperature, in solution and in the solid state. The emissions are assigned to intraligand transitions associated with the C=C moieties or related to 3[s(Au–P)¿p*(C=Cpy)] transitions. The crystal structure of dinuclear complex [Au2{C=C(CH2)3C=C}(PPh2py)2] shows the presence of dimers stabilized by intermolecular aurophilic interactions.
000079327 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E77$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2016-75816-C2-1-P
000079327 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000079327 590__ $$a2.578$$b2018
000079327 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b15 / 45 = 0.333$$c2018$$dQ2$$eT2
000079327 592__ $$a0.736$$b2018
000079327 593__ $$aInorganic Chemistry$$c2018$$dQ2
000079327 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000079327 700__ $$aCámara, J.
000079327 700__ $$0(orcid)0000-0002-1218-7218$$aFernández-Moreira, V.
000079327 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, A.$$uUniversidad de Zaragoza
000079327 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M.C.$$uUniversidad de Zaragoza
000079327 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000079327 773__ $$g2018, 24 (2018), 2762-2767$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000079327 8564_ $$s630468$$uhttps://zaguan.unizar.es/record/79327/files/texto_completo.pdf$$yPostprint
000079327 8564_ $$s19054$$uhttps://zaguan.unizar.es/record/79327/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000079327 909CO $$ooai:zaguan.unizar.es:79327$$particulos$$pdriver
000079327 951__ $$a2023-11-27-09:46:32
000079327 980__ $$aARTICLE