000079705 001__ 79705
000079705 005__ 20200716101441.0
000079705 0247_ $$2doi$$a10.1016/j.jct.2018.07.031
000079705 0248_ $$2sideral$$a107333
000079705 037__ $$aART-2019-107333
000079705 041__ $$aeng
000079705 100__ $$aLapeña, D.
000079705 245__ $$aThe NADES glyceline as a potential Green Solvent: A comprehensive study of its thermophysical properties and effect of water inclusion
000079705 260__ $$c2019
000079705 5060_ $$aAccess copy available to the general public$$fUnrestricted
000079705 5203_ $$aIn this paper, two Natural Deep Eutectic Solvents, glyceline (Gly) and glyceline-water (GlyW), containing choline chloride as acceptor H-bond compound and glycerol as donor H-bond group are studied. For glyceline the mole relation is 1 (choline chloride): 2 (glycerol) and for glyceline-water the mole relation is 1 (choline chloride): 1.99 (glycerol): 1.02 water. The ternary NADES has been synthetized and characterized chemically by NMR techniques for this work. Several thermophysical properties in a wide range of temperature (278.15–338.15)¿K and at atmospheric pressure (0.1¿MPa) have been measured for both compounds: density, , speed of sound, , refractive index, , surface tension,, isobaric molar heat capacity, , kinematic viscosity, , and electric conductivity,. Furthermore, some related properties have been also calculated: isobaric expansibility, , isentropic compressibility, , molar refraction, , entropy and enthalpy of surface formationper unit surface area ( and ), and dynamic viscosity, , and viscous flow and electrical conductivity activation energies. The results have been discussed in terms of the effect of temperature and the inclusion of water. We conclude that the compound containing water into the structure has a higher molar volume and a higher fluidity. The binary NADES (Gly) is a more structured liquid than ternary one (GlyW).
000079705 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E31-17R
000079705 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000079705 590__ $$a2.888$$b2019
000079705 592__ $$a0.787$$b2019
000079705 591__ $$aTHERMODYNAMICS$$b14 / 61 = 0.23$$c2019$$dQ1$$eT1
000079705 593__ $$aAtomic and Molecular Physics, and Optics$$c2019$$dQ2
000079705 591__ $$aCHEMISTRY, PHYSICAL$$b77 / 158 = 0.487$$c2019$$dQ2$$eT2
000079705 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ2
000079705 593__ $$aMaterials Science (miscellaneous)$$c2019$$dQ2
000079705 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000079705 700__ $$aLomba, L.
000079705 700__ $$0(orcid)0000-0003-1810-9488$$aArtal, M.$$uUniversidad de Zaragoza
000079705 700__ $$0(orcid)0000-0003-3632-6822$$aLafuente, C.$$uUniversidad de Zaragoza
000079705 700__ $$0(orcid)0000-0001-8669-2789$$aGiner, B.
000079705 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000079705 773__ $$g128 (2019), 164-172$$pJ. Chem. Thermodyn.$$tJOURNAL OF CHEMICAL THERMODYNAMICS$$x0021-9614
000079705 8564_ $$s363409$$uhttps://zaguan.unizar.es/record/79705/files/texto_completo.pdf$$yPostprint
000079705 8564_ $$s28335$$uhttps://zaguan.unizar.es/record/79705/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000079705 909CO $$ooai:zaguan.unizar.es:79705$$particulos$$pdriver
000079705 951__ $$a2020-07-16-08:59:42
000079705 980__ $$aARTICLE