79705 20200716101441.0 doi 10.1016/j.jct.2018.07.031 sideral 107333 ART-2019-107333 eng Lapeña, D. The NADES glyceline as a potential Green Solvent: A comprehensive study of its thermophysical properties and effect of water inclusion 2019 Access copy available to the general public Unrestricted In this paper, two Natural Deep Eutectic Solvents, glyceline (Gly) and glyceline-water (GlyW), containing choline chloride as acceptor H-bond compound and glycerol as donor H-bond group are studied. For glyceline the mole relation is 1 (choline chloride): 2 (glycerol) and for glyceline-water the mole relation is 1 (choline chloride): 1.99 (glycerol): 1.02 water. The ternary NADES has been synthetized and characterized chemically by NMR techniques for this work. Several thermophysical properties in a wide range of temperature (278.15–338.15)¿K and at atmospheric pressure (0.1¿MPa) have been measured for both compounds: density, , speed of sound, , refractive index, , surface tension,, isobaric molar heat capacity, , kinematic viscosity, , and electric conductivity,. Furthermore, some related properties have been also calculated: isobaric expansibility, , isentropic compressibility, , molar refraction, , entropy and enthalpy of surface formationper unit surface area ( and ), and dynamic viscosity, , and viscous flow and electrical conductivity activation energies. The results have been discussed in terms of the effect of temperature and the inclusion of water. We conclude that the compound containing water into the structure has a higher molar volume and a higher fluidity. The binary NADES (Gly) is a more structured liquid than ternary one (GlyW). info:eu-repo/grantAgreement/ES/DGA/E31-17R info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 2.888 2019 0.787 2019 THERMODYNAMICS 14 / 61 = 0.23 2019 Q1 T1 Atomic and Molecular Physics, and Optics 2019 Q2 CHEMISTRY, PHYSICAL 77 / 158 = 0.487 2019 Q2 T2 Physical and Theoretical Chemistry 2019 Q2 Materials Science (miscellaneous) 2019 Q2 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Lomba, L. (orcid)0000-0003-1810-9488 Artal, M. Universidad de Zaragoza (orcid)0000-0003-3632-6822 Lafuente, C. Universidad de Zaragoza (orcid)0000-0001-8669-2789 Giner, B. 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 128 (2019), 164-172 J. Chem. Thermodyn. JOURNAL OF CHEMICAL THERMODYNAMICS 0021-9614 363409 http://zaguan.unizar.es/record/79705/files/texto_completo.pdf Postprint 28335 http://zaguan.unizar.es/record/79705/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:79705 articulos driver 2020-07-16-08:59:42 ARTICLE