Solvent-Free Encapsulation at High Pressure with Carboxylate-Based MOFs

Monteagudo-Olivan, R. ; Paseta, L. (Universidad de Zaragoza) ; Potier, G. ; López-Ram-de-Viu, P. (Universidad de Zaragoza) ; Coronas, J. (Universidad de Zaragoza)

Resumen: The solvent-free encapsulation of caffeine and kojic acid was carried out in different carboxylate-based MOFs [MIL-53(Al), UiO-66 and Mg-MOF-74] by high pressure (0.32 GPa) contact. This methodology enables fast and ecofriendly encapsulation and gives rise to additive@MOFs with physical and features equivalent to those of materials obtained by common liquid phase encapsulation processes. It could be applied to other host–guest systems, simplifying the procedures, reducing the use and waste of harmful chemicals, and approaching the conditions of interest in the industry. The characterization carried out by thermogravimetry, X-ray diffraction, N2 adsorption, and 13C NMR provided information about the presence and conformation of the additives in the MOFs. The highest encapsulation values for caffeine (37 %) and kojic acid (32 %) were obtained with MIL-53(Al).

Idioma: Inglés

DOI: 10.1002/ejic.201800985

Año: 2019

Publicado en: European Journal of Inorganic Chemistry 2019, 1 (2019), 29-36
ISSN: 1434-1948

Factor impacto JCR: 2.529 (2019)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 16 / 45 = 0.356 (2019) - Q2 - T2

Factor impacto SCIMAGO: 0.693 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/T43-17R

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Química Orgánica (Dpto. Química Orgánica)