000086387 001__ 86387
000086387 005__ 20200716101601.0
000086387 0247_ $$2doi$$a10.3390/cryst9060316
000086387 0248_ $$2sideral$$a115078
000086387 037__ $$aART-2019-115078
000086387 041__ $$aeng
000086387 100__ $$aRodríguez-Velamazán, José Alberto
000086387 245__ $$aStructural insights into the two-step spin-crossover compound Fe(3, 4-dimethyl-pyridine)2[Ag(CN)2]2
000086387 260__ $$c2019
000086387 5060_ $$aAccess copy available to the general public$$fUnrestricted
000086387 5203_ $$aThe crystal structure of the polymeric spin crossover compound Fe(3, 4-dimethyl-pyridine)2[Ag(CN)2]2 has been solved and its temperature dependence followed by means of single-crystal and powder X-ray diffraction. This compound presents a two-step spin transition with relatively abrupt steps centred at ca. 170 K and 145 K and a plateau at around 155 K. The origin of the two-step transition is discussed in light of these structural studies. The observations are compatible with a mostly disordered state between the two steps, consisting of mixing of high-spin and low-spin species, while weak substructure reflections in the mixed phase could indicate some degree of long-range order of the high-spin and low-spin sites.
000086387 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E11-17R$$9info:eu-repo/grantAgreement/ES/MICINN/MAT2017-86019-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2015-68200-C2-2-P
000086387 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000086387 590__ $$a2.404$$b2019
000086387 591__ $$aCRYSTALLOGRAPHY$$b10 / 26 = 0.385$$c2019$$dQ2$$eT2
000086387 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b165 / 314 = 0.525$$c2019$$dQ3$$eT2
000086387 592__ $$a0.594$$b2019
000086387 593__ $$aChemical Engineering (miscellaneous)$$c2019$$dQ2
000086387 593__ $$aMaterials Science (miscellaneous)$$c2019$$dQ2
000086387 593__ $$aInorganic Chemistry$$c2019$$dQ2
000086387 593__ $$aCondensed Matter Physics$$c2019$$dQ2
000086387 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000086387 700__ $$aKitase, Kosuke
000086387 700__ $$0(orcid)0000-0003-3567-7030$$aPalacios, Elías$$uUniversidad de Zaragoza
000086387 700__ $$0(orcid)0000-0002-9687-4903$$aCastro, Miguel$$uUniversidad de Zaragoza
000086387 700__ $$aFernández-Blanco, Ángel
000086387 700__ $$0(orcid)0000-0003-2962-9251$$aBurriel, Ramón$$uUniversidad de Zaragoza
000086387 700__ $$aKitazawa, Takafumi
000086387 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000086387 7102_ $$15001$$2065$$aUniversidad de Zaragoza$$bDpto. Ciencia Tecnol.Mater.Fl.$$cÁrea Cienc.Mater. Ingen.Metal.
000086387 773__ $$g9, 6 (2019), 316 [8 pp.]$$pCrystals$$tCrystals$$x2073-4352
000086387 8564_ $$s870491$$uhttps://zaguan.unizar.es/record/86387/files/texto_completo.pdf$$yVersión publicada
000086387 8564_ $$s108515$$uhttps://zaguan.unizar.es/record/86387/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000086387 909CO $$ooai:zaguan.unizar.es:86387$$particulos$$pdriver
000086387 951__ $$a2020-07-16-09:52:51
000086387 980__ $$aARTICLE