000086443 001__ 86443 000086443 005__ 20200716101510.0 000086443 0247_ $$2doi$$a10.1016/j.jct.2018.12.027 000086443 0248_ $$2sideral$$a110349 000086443 037__ $$aART-2019-110349 000086443 041__ $$aeng 000086443 100__ $$0(orcid)0000-0001-9379-8047$$aMainar, A.M.$$uUniversidad de Zaragoza 000086443 245__ $$aSolubility of gases in fluoroorganic alcohols. Part III. Solubilities of several non-polar gases in water¿+¿1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol at 298.15¿K and 101.33¿kPa 000086443 260__ $$c2019 000086443 5060_ $$aAccess copy available to the general public$$fUnrestricted 000086443 5203_ $$aSolubilities of the non-polar gases H2, N2, O2, CH4, C2H6, C2H4, CF4, SF6, and CO2 in the mixture (water + 1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol) at the temperature of 298.15 K and 101.33 kPa partial pressure of gas are reported. A polynomial dependence of the solubilities on the molar fraction of the binary liquid mixture is found. The Henry''s constants at the vapor pressure of water, the standard changes in the Gibbs energy for the solution process and for the solvation process, and the so-called excess Henry''s constant are calculated. The results have been compared with those obtained by Scaled Particle Theory (SPT). A method to compare the solubility of a gas in different liquids is proposed and applied to 2, 2, 2-trifluoroethanol and 1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol. 000086443 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E39-17R$$9info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragón$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-64049-C3-2-R 000086443 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/ 000086443 590__ $$a2.888$$b2019 000086443 591__ $$aTHERMODYNAMICS$$b14 / 61 = 0.23$$c2019$$dQ1$$eT1 000086443 591__ $$aCHEMISTRY, PHYSICAL$$b77 / 158 = 0.487$$c2019$$dQ2$$eT2 000086443 592__ $$a0.787$$b2019 000086443 593__ $$aAtomic and Molecular Physics, and Optics$$c2019$$dQ2 000086443 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ2 000086443 593__ $$aMaterials Science (miscellaneous)$$c2019$$dQ2 000086443 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000086443 700__ $$0(orcid)0000-0001-6182-2196$$aMartínez-López, J.F.$$uUniversidad de Zaragoza 000086443 700__ $$0(orcid)0000-0001-7569-5036$$aUrieta, J.S. 000086443 700__ $$0(orcid)0000-0002-0661-9889$$aPardo, J.I.$$uUniversidad de Zaragoza 000086443 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física 000086443 773__ $$g132 (2019), 229-239$$pJ. Chem. Thermodyn.$$tJOURNAL OF CHEMICAL THERMODYNAMICS$$x0021-9614 000086443 8564_ $$s975929$$uhttps://zaguan.unizar.es/record/86443/files/texto_completo.pdf$$yVersión publicada 000086443 8564_ $$s204269$$uhttps://zaguan.unizar.es/record/86443/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000086443 909CO $$ooai:zaguan.unizar.es:86443$$particulos$$pdriver 000086443 951__ $$a2020-07-16-09:18:22 000086443 980__ $$aARTICLE