86443 20200716101510.0 doi 10.1016/j.jct.2018.12.027 sideral 110349 ART-2019-110349 eng (orcid)0000-0001-9379-8047 Mainar, A.M. Universidad de Zaragoza Solubility of gases in fluoroorganic alcohols. Part III. Solubilities of several non-polar gases in water¿+¿1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol at 298.15¿K and 101.33¿kPa 2019 Access copy available to the general public Unrestricted Solubilities of the non-polar gases H2, N2, O2, CH4, C2H6, C2H4, CF4, SF6, and CO2 in the mixture (water + 1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol) at the temperature of 298.15 K and 101.33 kPa partial pressure of gas are reported. A polynomial dependence of the solubilities on the molar fraction of the binary liquid mixture is found. The Henry''s constants at the vapor pressure of water, the standard changes in the Gibbs energy for the solution process and for the solvation process, and the so-called excess Henry''s constant are calculated. The results have been compared with those obtained by Scaled Particle Theory (SPT). A method to compare the solubility of a gas in different liquids is proposed and applied to 2, 2, 2-trifluoroethanol and 1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol. info:eu-repo/grantAgreement/ES/DGA/E39-17R info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragón info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-64049-C3-2-R info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 2.888 2019 THERMODYNAMICS 14 / 61 = 0.23 2019 Q1 T1 CHEMISTRY, PHYSICAL 77 / 158 = 0.487 2019 Q2 T2 0.787 2019 Atomic and Molecular Physics, and Optics 2019 Q2 Physical and Theoretical Chemistry 2019 Q2 Materials Science (miscellaneous) 2019 Q2 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion (orcid)0000-0001-6182-2196 Martínez-López, J.F. Universidad de Zaragoza (orcid)0000-0001-7569-5036 Urieta, J.S. (orcid)0000-0002-0661-9889 Pardo, J.I. Universidad de Zaragoza 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 132 (2019), 229-239 J. Chem. Thermodyn. JOURNAL OF CHEMICAL THERMODYNAMICS 0021-9614 975929 http://zaguan.unizar.es/record/86443/files/texto_completo.pdf Versión publicada 204269 http://zaguan.unizar.es/record/86443/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:86443 articulos driver 2020-07-16-09:18:22 ARTICLE