doi:10.1016/j.dyepig.2018.12.066engColom, E.Andrés-Castán, J.M.Barrios, D.Duerto, I.Franco, S.Garín, J.Orduna, J.Villacampa, B.Blesa, M.J.Modification of the electronic properties of the p-spacer of chromophores linked to calix[4]arene platform for DSSCs applicationsART-2019-110350We have developed two novel dyes based on p-tert-butyl-calix[4]arene in order to evaluate their behavior as sensitizer in photovoltaic devices. These dyes consist in a difunctionalized calix[4]arene with triphenylamine (TPA)-donor, a heteroaromatic π-conjugated spacer, thiophene and benzothiadiazole-phenyl ring, respectively and cyanoacetic acid as acceptor group. The effect of the π-spacer has been studied by UV–vis spectroscopy and Differential Pulse Voltammetry and the models compounds have been theoretically investigated. The dye bearing phenylbenzothiadiazole results in a bathochromic shifted absorption and an adequate efficiency to transfer charge from D to A. The considerable increase of the photocurrent density results in a better efficiency of the devices prepared with these novel dyes with respect to the p-tert-butyl-calix[4]arene derivatives bearing TPA dye. In particular, p-tert-butyl-calix[4]arene derivative based on phenylbenzothiadiazole has reached an efficiency value of 5.84% which means an increase of 33% of the efficiency over those calix[4]arene derivatives with TPA dye.2019http://zaguan.unizar.es/record/8644410.1016/j.dyepig.2018.12.066http://zaguan.unizar.es/record/86444oai:zaguan.unizar.es:86444info:eu-repo/grantAgreement/ES/DGA/E14-17Rinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52331-RDyes and Pigments 164 (2019), 43-53by-nc-ndhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccess