doi:10.1021/acs.inorgchem.8b03366engEsteruelas, M.A.Fernández, I.García-Yebra, C.Martín, J.Oñate, E.Cycloosmathioborane Compounds: Other Manifestations of the Hückel AromaticityART-2019-110659The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH 3 NHR 2 amine-borane, bear an Os-S-B three-membered ring, being a manifestation of the 4n + 2 Hückel aromaticity in which n = 0 and where the two p electrons of the ring are provided by the S atom.2019http://zaguan.unizar.es/record/8753010.1021/acs.inorgchem.8b03366http://zaguan.unizar.es/record/87530oai:zaguan.unizar.es:87530info:eu-repo/grantAgreement/ES/DGA/E06-17Rinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2016-78205-Pinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2016-81797-REDCinfo:eu-repo/grantAgreement/ES/MINECO/CTQ2017-82935-PInorganic Chemistry 58, 4 (2019), 2265-2269All rights reservedhttp://www.europeana.eu/rights/rr-f/info:eu-repo/semantics/openAccess