87693 20200716101433.0 doi 10.1016/j.combustflame.2019.01.017 sideral 110880 ART-2019-110880 eng (orcid)0000-0003-4679-5761 Alzueta, M.U. Universidad de Zaragoza CH3SH conversion in a tubular flow reactor. Experiments and kinetic modelling 2019 Access copy available to the general public Unrestricted The use of non-conventional fuel sources, such as shale gas, brings new research requisites for its proper use in an environmental friendly manner. In this context, shale gas may include different sulphur containing compounds, such as methanethiol, that is also formed as intermediate during sulphur containing residues processing. The present work includes an experimental and kinetic modelling study of the oxidation of methanethiol, CH3SH, in a quartz flow tubular reactor at atmospheric pressure and in the 300–1400 K temperature range. The influence of the temperature, the O2 concentration and the presence of H2O on the conversion regime of CH3SH and the formation of different compounds has been analysed. The experimental results have been interpreted in terms of a detailed gas-phase mechanism compiled in the present work, and the elementary steps involved in the conversion of CH3SH have been identified. In general, oxidation of CH3SH is favoured by both oxygen level and temperature, while the presence of H2O does not modify the CH3SH conversion profile. The main sulphur containing products are SO2, H2S and CS2, pointing to a significant role of other products, apart from SO2, for the control of pollutant emissions. info:eu-repo/grantAgreement/ES/DGA/GPT info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-65226 info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 4.57 2019 2.079 2019 ENGINEERING, MECHANICAL 15 / 130 = 0.115 2019 Q1 T1 Chemical Engineering (miscellaneous) 2019 Q1 ENGINEERING, CHEMICAL 27 / 143 = 0.189 2019 Q1 T1 Chemistry (miscellaneous) 2019 Q1 ENGINEERING, MULTIDISCIPLINARY 11 / 91 = 0.121 2019 Q1 T1 Physics and Astronomy (miscellaneous) 2019 Q1 THERMODYNAMICS 7 / 61 = 0.115 2019 Q1 T1 Fuel Technology 2019 Q1 ENERGY & FUELS 36 / 112 = 0.321 2019 Q2 T1 Energy Engineering and Power Technology 2019 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Pernía, R. (orcid)0000-0001-7559-9669 Abián, M. Universidad de Zaragoza (orcid)0000-0001-5426-6486 Millera, Á. Universidad de Zaragoza (orcid)0000-0002-5420-0943 Bilbao, R. Universidad de Zaragoza 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 5005 790 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Tecnologi. Medio Ambiente 203 (2019), 23-30 Combust. flame Combustion and Flame 0010-2180 325752 http://zaguan.unizar.es/record/87693/files/texto_completo.pdf Postprint 265846 http://zaguan.unizar.es/record/87693/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:87693 articulos driver 2020-07-16-08:52:29 ARTICLE