000087701 001__ 87701
000087701 005__ 20200716101450.0
000087701 0247_ $$2doi$$a10.1039/c8ob03201g
000087701 0248_ $$2sideral$$a111283
000087701 037__ $$aART-2019-111283
000087701 041__ $$aeng
000087701 100__ $$0(orcid)0000-0001-9779-5820$$aUrriolabeitia, E.P.$$uUniversidad de Zaragoza
000087701 245__ $$aRu(ii)-Catalysed synthesis of (1 H)-isothiochromenes by oxidative coupling of benzylthioethers with internal alkynes
000087701 260__ $$c2019
000087701 5060_ $$aAccess copy available to the general public$$fUnrestricted
000087701 5203_ $$aThe synthesis of 1H-isothiochromenes by oxidative coupling of benzyl(tert-butyl)thioethers with internal alkynes, catalysed by Ru(ii), has been achieved. The reaction occurs by S-directed C-H activation at the ortho position of the aryl ring, promoted by ruthenium, migratory insertion of the alkyne, 1, 2-thio-Wittig rearrangement of the tert-butyl group and reductive elimination by C-S coupling between the resulting anionic sulfide and the vinylic carbon.
000087701 536__ $$9info:eu-repo/grantAgreement/EUR/COST/CA15106-CHAOS$$9info:eu-repo/grantAgreement/ES/DGA-FEDER/E19-17R
000087701 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000087701 590__ $$a3.412$$b2019
000087701 591__ $$aCHEMISTRY, ORGANIC$$b13 / 57 = 0.228$$c2019$$dQ1$$eT1
000087701 592__ $$a0.969$$b2019
000087701 593__ $$aOrganic Chemistry$$c2019$$dQ1
000087701 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ1
000087701 593__ $$aBiochemistry$$c2019$$dQ2
000087701 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000087701 700__ $$0(orcid)0000-0002-6766-9214$$aRuiz, S.
000087701 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000087701 773__ $$g17, 9 (2019), 2542-2547$$pOrg. biomol. chem.$$tORGANIC & BIOMOLECULAR CHEMISTRY$$x1477-0520
000087701 8564_ $$s576541$$uhttps://zaguan.unizar.es/record/87701/files/texto_completo.pdf$$yPostprint
000087701 8564_ $$s68017$$uhttps://zaguan.unizar.es/record/87701/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000087701 909CO $$ooai:zaguan.unizar.es:87701$$particulos$$pdriver
000087701 951__ $$a2020-07-16-09:05:34
000087701 980__ $$aARTICLE