000087830 001__ 87830
000087830 005__ 20200716101426.0
000087830 0247_ $$2doi$$a10.1021/acs.iecr.8b06017
000087830 0248_ $$2sideral$$a111199
000087830 037__ $$aART-2019-111199
000087830 041__ $$aeng
000087830 100__ $$0(orcid)0000-0003-2006-1495$$aPaseta, L.$$uUniversidad de Zaragoza
000087830 245__ $$a110th Anniversary: Polyamide/Metal-Organic Framework Bilayered Thin Film Composite Membranes for the Removal of Pharmaceutical Compounds from Water
000087830 260__ $$c2019
000087830 5060_ $$aAccess copy available to the general public$$fUnrestricted
000087830 5203_ $$aNanofiltration can be a useful tool to remove pharmaceuticals in water sources. The performance of the most used thin film composite (TFC) membranes, typically with a thin polyamide (PA) layer, can be improved using thin film nanocomposite (TFN) membranes obtained by the introduction of a filler within the PA layer. In this work, to control the positioning of the filler two kinds of PA/metal-organic framework (MOF) bilayered TFC (BTFC) membranes, PA/ZIF-93 and PA/HKUST-1, were synthesized onto polyimide supports. First, the interfacial synthesis was used for the preparation of a MOF layer, and second, a PA layer was synthesized by interfacial polymerization. These BTFC membranes were applied in the nanofiltration of diclofenac and naproxen aqueous solutions obtaining a maximum water permeance of 33.1 and 24.9 L·m -2 ·h -1 ·bar -1 , respectively, with a rejection of =98% when HKUST-1 was used. These permeance improvements (using diclofenac, 4.9 and 3.4 times the value of the TFC and TFN membranes, respectively) are related to the PA layer thickness, MOF porosity, membrane hydrophilicity, and membrane roughness.
000087830 536__ $$9info:eu-repo/grantAgreement/ES/DGA/FSE$$9info:eu-repo/grantAgreement/ES/DGA/T43-17R$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/MAT2016-77290-R$$9info:eu-repo/grantAgreement/ES/MINECO/FPI2014
000087830 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000087830 590__ $$a3.573$$b2019
000087830 592__ $$a0.899$$b2019
000087830 591__ $$aENGINEERING, CHEMICAL$$b44 / 143 = 0.308$$c2019$$dQ2$$eT1
000087830 593__ $$aChemical Engineering (miscellaneous)$$c2019$$dQ1
000087830 593__ $$aIndustrial and Manufacturing Engineering$$c2019$$dQ1
000087830 593__ $$aChemistry (miscellaneous)$$c2019$$dQ1
000087830 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000087830 700__ $$aAntorán, D.
000087830 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000087830 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, C.$$uUniversidad de Zaragoza
000087830 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000087830 773__ $$g58, 10 (2019), 4222-4230$$pInd. eng. chem. res.$$tINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH$$x0888-5885
000087830 8564_ $$s778780$$uhttps://zaguan.unizar.es/record/87830/files/texto_completo.pdf$$yPostprint
000087830 8564_ $$s286460$$uhttps://zaguan.unizar.es/record/87830/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000087830 909CO $$ooai:zaguan.unizar.es:87830$$particulos$$pdriver
000087830 951__ $$a2020-07-16-08:44:49
000087830 980__ $$aARTICLE