000088161 001__ 88161
000088161 005__ 20200716101425.0
000088161 0247_ $$2doi$$a10.1016/j.ica.2019.02.033
000088161 0248_ $$2sideral$$a111191
000088161 037__ $$aART-2019-111191
000088161 041__ $$aeng
000088161 100__ $$aCifuentes-Vaca, O.L.
000088161 245__ $$aSilver(I) and copper(I) complexes with a Schiff base derived from 2-aminofluorene with promising antibacterial activity
000088161 260__ $$c2019
000088161 5060_ $$aAccess copy available to the general public$$fUnrestricted
000088161 5203_ $$aBy reaction of 2-aminofluorene with 2-pyridinecarboxaldehyde a new Schiff base (L) is obtained. The reaction of this ligand with Ag(I) and Cu(I) salts in different stoichiometry leads to the complexes [Ag(CF 3 SO 3 )(L)PPh 3 ] (1) or [ML 2 ]A (M = Ag, Cu; A = CF 3 SO 3 , ClO 4 or BF 4 ). Structural characterization by X-ray crystallography has been carried out for complexes [AgL 2 ]ClO 4 (4) and [Ag(L)(PPh 3 ) 2 ](CF 3 SO 3 ) (6), which confirms the chelate nature of L and the presence of Ag¿H interactions between two molecules. The biological studies show that Schiff base L presents antibacterial activity in Gram-positive bacteria and E. coli. The coordination to silver increases this activity, but the formation of the copper complex does not generate significant changes.
000088161 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-75816-C2-1-P
000088161 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000088161 590__ $$a2.304$$b2019
000088161 592__ $$a0.447$$b2019
000088161 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b20 / 45 = 0.444$$c2019$$dQ2$$eT2
000088161 593__ $$aMaterials Chemistry$$c2019$$dQ2
000088161 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ3
000088161 593__ $$aInorganic Chemistry$$c2019$$dQ3
000088161 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000088161 700__ $$aAndrades-Lagos, J.
000088161 700__ $$aCampanini-Salinas, J.
000088161 700__ $$0(orcid)0000-0003-1984-7538$$aLaguna, A.$$uUniversidad de Zaragoza
000088161 700__ $$aVásquez-Velásquez, D.
000088161 700__ $$0(orcid)0000-0003-0553-0695$$aConcepción Gimeno, M.$$uUniversidad de Zaragoza
000088161 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000088161 773__ $$g489 (2019), 275-279$$pInorg. Chim. Acta$$tINORGANICA CHIMICA ACTA$$x0020-1693
000088161 8564_ $$s655846$$uhttps://zaguan.unizar.es/record/88161/files/texto_completo.pdf$$yPostprint
000088161 8564_ $$s216570$$uhttps://zaguan.unizar.es/record/88161/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000088161 909CO $$ooai:zaguan.unizar.es:88161$$particulos$$pdriver
000088161 951__ $$a2020-07-16-08:44:05
000088161 980__ $$aARTICLE