Heterobimetallic ruthenium–zinc complexes with bulky N-heterocyclic carbenes: syntheses, structures and reactivity

Espinal-Viguri, Maialen ; Varela-Izquierdo, Victor ; Miloserdov, Fedor M ; Riddlestone, Ian M ; Mahon, Mary F ; Whittlesey, Michael K.

Resumen: The ruthenium–zinc heterobimetallic complexes, [Ru(IPr)2(CO)ZnMe][BArF4] (7), [Ru(IBiox6)2(CO)(THF) ZnMe][BArF4] (12) and [Ru(IMes)’(PPh3)(CO)ZnMe] (15), have been prepared by reaction of ZnMe2 with the ruthenium N-heterocyclic carbene complexes [Ru(IPr)2(CO)H][BArF4] (1), [Ru(IBiox6)2(CO)(THF)H][BArF4] (11) and [Ru(IMes)(PPh3)(CO)HCl] respectively. 7 shows clean reactivity towards H2, yielding [Ru(IPr)2(CO) (¿2-H2)(H)2ZnMe][BArF4] (8), which undergoes loss of the coordinated dihydrogen ligand upon application of vacuum to form [Ru(IPr)2(CO)(H)2ZnMe][BArF4] (9). In contrast, addition of H2 to 12 gave only a mixture of products. The tetramethyl IBiox complex [Ru(IBioxMe4)2(CO)(THF)H][BArF4] (14) failed to give any isol- able Ru–Zn containing species upon reaction with ZnMe2. The cyclometallated NHC complex [Ru(IMes)’ (PPh3)(CO)ZnMe] (15) added H2 across the Ru–Zn bond both in solution and in the solid-state to afford [Ru(IMes)’(PPh3)(CO)(H)2ZnMe] (17), with retention of the cyclometallatio

Idioma: Inglés

DOI: 10.1039/c8dt05023f

Año: 2019

Publicado en: Dalton Transactions 48, 13 (2019), 4176-4189
ISSN: 1477-9226

Factor impacto JCR: 4.174 (2019)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 5 / 45 = 0.111 (2019) - Q1 - T1

Factor impacto SCIMAGO: 1.048 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E08-17R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2017-83421-P

Tipo y forma: Artículo (Versión definitiva)