000089719 001__ 89719
000089719 005__ 20200716101422.0
000089719 0247_ $$2doi$$a10.1016/j.jorganchem.2019.06.010
000089719 0248_ $$2sideral$$a112585
000089719 037__ $$aART-2019-112585
000089719 041__ $$aeng
000089719 100__ $$0(orcid)0000-0001-9340-5952$$aGuzmán, Jefferson$$uUniversidad de Zaragoza
000089719 245__ $$aRhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes
000089719 260__ $$c2019
000089719 5060_ $$aAccess copy available to the general public$$fUnrestricted
000089719 5203_ $$aThe reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(¿2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(¿2-CF3CO2)(¿2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized by elemental analysis and NMR spectroscopy. The solid-state structure of 3 has been confirmed by X-ray diffraction analysis. Moreover, the activity of complex 3 as catalyst for the reaction of secondary amines with CO2 (3¿bar) and hydrosilanes has been studied. The outcomes of these catalytic studies show that under these conditions complex 3 promotes the selective formation of silylcarbamates.
000089719 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17R$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67366-P
000089719 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000089719 590__ $$a2.304$$b2019
000089719 592__ $$a0.506$$b2019
000089719 591__ $$aCHEMISTRY, ORGANIC$$b26 / 57 = 0.456$$c2019$$dQ2$$eT2
000089719 593__ $$aMaterials Chemistry$$c2019$$dQ2
000089719 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b20 / 45 = 0.444$$c2019$$dQ2$$eT2
000089719 593__ $$aInorganic Chemistry$$c2019$$dQ2
000089719 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ2
000089719 593__ $$aOrganic Chemistry$$c2019$$dQ2
000089719 593__ $$aBiochemistry$$c2019$$dQ3
000089719 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000089719 700__ $$aTorguet, Adrían
000089719 700__ $$0(orcid)0000-0002-7063-1292$$aGarcía-Orduña, Pilar$$uUniversidad de Zaragoza
000089719 700__ $$0(orcid)0000-0001-8054-2237$$aLahoz, Fernando J.$$uUniversidad de Zaragoza
000089719 700__ $$0(orcid)0000-0001-7154-7239$$aOro, Luis A.$$uUniversidad de Zaragoza
000089719 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Alvarez, Francisco J.$$uUniversidad de Zaragoza
000089719 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000089719 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000089719 773__ $$g897 (2019), 50-56 [25 pp.]$$pJ. organomet. chem.$$tJournal of Organometallic Chemistry$$x0022-328X
000089719 8564_ $$s309722$$uhttps://zaguan.unizar.es/record/89719/files/texto_completo.pdf$$yPostprint
000089719 8564_ $$s116569$$uhttps://zaguan.unizar.es/record/89719/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000089719 909CO $$ooai:zaguan.unizar.es:89719$$particulos$$pdriver
000089719 951__ $$a2020-07-16-08:42:06
000089719 980__ $$aARTICLE