doi:10.1016/j.jorganchem.2019.06.010engGuzmán, JeffersonTorguet, AdríanGarcía-Orduña, PilarLahoz, Fernando J.Oro, Luis A.Fernández-Alvarez, Francisco J.Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanesART-2019-112585The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(¿2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(¿2-CF3CO2)(¿2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized by elemental analysis and NMR spectroscopy. The solid-state structure of 3 has been confirmed by X-ray diffraction analysis. Moreover, the activity of complex 3 as catalyst for the reaction of secondary amines with CO2 (3¿bar) and hydrosilanes has been studied. The outcomes of these catalytic studies show that under these conditions complex 3 promotes the selective formation of silylcarbamates.2019http://zaguan.unizar.es/record/8971910.1016/j.jorganchem.2019.06.010http://zaguan.unizar.es/record/89719oai:zaguan.unizar.es:89719info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17Rinfo:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67366-PJournal of Organometallic Chemistry 897 (2019), 50-56 [25 pp.]by-nc-ndhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccess