89719 20200716101422.0 doi 10.1016/j.jorganchem.2019.06.010 sideral 112585 ART-2019-112585 eng (orcid)0000-0001-9340-5952 Guzmán, Jefferson Universidad de Zaragoza Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes 2019 Access copy available to the general public Unrestricted The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(¿2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(¿2-CF3CO2)(¿2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized by elemental analysis and NMR spectroscopy. The solid-state structure of 3 has been confirmed by X-ray diffraction analysis. Moreover, the activity of complex 3 as catalyst for the reaction of secondary amines with CO2 (3¿bar) and hydrosilanes has been studied. The outcomes of these catalytic studies show that under these conditions complex 3 promotes the selective formation of silylcarbamates. info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17R info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67366-P info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 2.304 2019 0.506 2019 CHEMISTRY, ORGANIC 26 / 57 = 0.456 2019 Q2 T2 Materials Chemistry 2019 Q2 CHEMISTRY, INORGANIC & NUCLEAR 20 / 45 = 0.444 2019 Q2 T2 Inorganic Chemistry 2019 Q2 Physical and Theoretical Chemistry 2019 Q2 Organic Chemistry 2019 Q2 Biochemistry 2019 Q3 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Torguet, Adrían (orcid)0000-0002-7063-1292 García-Orduña, Pilar Universidad de Zaragoza (orcid)0000-0001-8054-2237 Lahoz, Fernando J. Universidad de Zaragoza (orcid)0000-0001-7154-7239 Oro, Luis A. Universidad de Zaragoza (orcid)0000-0002-0497-1969 Fernández-Alvarez, Francisco J. Universidad de Zaragoza 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 897 (2019), 50-56 [25 pp.] J. organomet. chem. Journal of Organometallic Chemistry 0022-328X 309722 http://zaguan.unizar.es/record/89719/files/texto_completo.pdf Postprint 116569 http://zaguan.unizar.es/record/89719/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:89719 articulos driver 2020-07-16-08:42:06 ARTICLE