000089880 001__ 89880
000089880 005__ 20200716101423.0
000089880 0247_ $$2doi$$a10.1016/j.ccr.2019.02.003
000089880 0248_ $$2sideral$$a111182
000089880 037__ $$aART-2019-111182
000089880 041__ $$aeng
000089880 100__ $$0(orcid)0000-0003-3144-5320$$aIglesias, Manuel$$uUniversidad de Zaragoza
000089880 245__ $$aNon-classical hydrosilane mediated reductions promoted by transition metal complexes
000089880 260__ $$c2019
000089880 5060_ $$aAccess copy available to the general public$$fUnrestricted
000089880 5203_ $$aThis article reviews the most recent advances on the study of non-classical mechanisms for the reduction of organic substrates with hydrosilanes catalyzed by transition metals. A wide variety of catalytic cycles that go beyond the classical steps described for Ojima, Chalk-Harrod and modified Chalk-Harrod mechanisms, as representative examples, have been proposed in recent years. In this review, these alternative mechanistic proposals have been analyzed and classified according to the type of substrate, focusing on the reduction/hydrosilylation of carbonyl compounds (ketones and aldehydes), carbon dioxide, silylesters, amides, N-heterocycles, alkyl halides, nitriles, alkenes and alkynes. In spite of the broad diversity of non-classical reaction mechanisms hitherto reported, the catalytic cycles described for each substrate have been arranged in different categories according to their characteristics. The epigraph dedicated to the first type of substrate (carbonyl compounds) comprises most of the mechanisms described in this review for the reduction of polar bonds, which, to some extent, show a relationship to those proposed for non-polar bonds (alkenes and alkynes). Remarkable types of reaction mechanisms that will be dealt with in this work are: ionic mechanisms, ligand-assisted mechanisms, nonhydride mechanisms, NHC-Cu-H mediated mechanisms, and silylene-mediated mechanisms.
000089880 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07$$9info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67366-P
000089880 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000089880 592__ $$a4.044$$b2019
000089880 590__ $$a15.367$$b2019
000089880 593__ $$aInorganic Chemistry$$c2019$$dQ1
000089880 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b1 / 45 = 0.022$$c2019$$dQ1$$eT1
000089880 593__ $$aPhysical and Theoretical Chemistry$$c2019$$dQ1
000089880 593__ $$aMaterials Chemistry$$c2019$$dQ1
000089880 655_4 $$ainfo:eu-repo/semantics/review$$vinfo:eu-repo/semantics/acceptedVersion
000089880 700__ $$0(orcid)0000-0002-0497-1969$$aFernández-Álvarez, Francisco J.$$uUniversidad de Zaragoza
000089880 700__ $$0(orcid)0000-0001-7154-7239$$aOro, Luis A.$$uUniversidad de Zaragoza
000089880 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000089880 773__ $$g386 (2019), 240-266$$pCoord. chem. rev.$$tCOORDINATION CHEMISTRY REVIEWS$$x0010-8545
000089880 8564_ $$s2799656$$uhttps://zaguan.unizar.es/record/89880/files/texto_completo.pdf$$yPostprint
000089880 8564_ $$s92399$$uhttps://zaguan.unizar.es/record/89880/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000089880 909CO $$ooai:zaguan.unizar.es:89880$$particulos$$pdriver
000089880 951__ $$a2020-07-16-08:42:55
000089880 980__ $$aARTICLE