000094478 001__ 94478
000094478 005__ 20210902121825.0
000094478 0247_ $$2doi$$a10.1021/acsnano.9b09284
000094478 0248_ $$2sideral$$a118329
000094478 037__ $$aART-2020-118329
000094478 041__ $$aeng
000094478 100__ $$0(orcid)0000-0002-9102-7895$$aHettler, S.
000094478 245__ $$aYS-TaS2 and YxLa1-xS-TaS2 (0 = x = 1) Nanotubes: A Family of Misfit Layered Compounds
000094478 260__ $$c2020
000094478 5060_ $$aAccess copy available to the general public$$fUnrestricted
000094478 5203_ $$aWe present the analysis of a family of nanotubes (NTs) based on the quaternary misfit layered compound (MLC) YxLa1-xS-TaS2. The NTs were successfully synthesized within the whole range of possible compositions via the chemical vapor transport technique. In-depth analysis of the NTs using electron microscopy and spectroscopy proves the in-phase (partial) substitution of La by Y in the (La, Y)S subsystem and reveals structural changes compared to the previously reported LaS-TaS2 MLC-NTs. The observed structure can be linked to the slightly different lattice parameters of LaS and YS. Raman spectroscopy and infrared transmission measurements reveal the tunability of the plasmonic and vibrational properties. Density-functional theory calculations showed that the YxLa1-xS-TaS2 MLCs are stable in all compositions. Moreover, the calculations indicated that substitution of La by Sc atoms is electronically not favorable, which explains our failed attempt to synthesize these MLC and NTs thereof.
000094478 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/MAT2016-79776-P$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 823717-ESTEEM3$$9info:eu-repo/grantAgreement/EC/H2020/823717/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM3
000094478 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000094478 590__ $$a15.881$$b2020
000094478 591__ $$aCHEMISTRY, PHYSICAL$$b12 / 162 = 0.074$$c2020$$dQ1$$eT1
000094478 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b11 / 106 = 0.104$$c2020$$dQ1$$eT1
000094478 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b14 / 178 = 0.079$$c2020$$dQ1$$eT1
000094478 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b21 / 333 = 0.063$$c2020$$dQ1$$eT1
000094478 592__ $$a5.554$$b2020
000094478 593__ $$aEngineering (miscellaneous)$$c2020$$dQ1
000094478 593__ $$aPhysics and Astronomy (miscellaneous)$$c2020$$dQ1
000094478 593__ $$aNanoscience and Nanotechnology$$c2020$$dQ1
000094478 593__ $$aMaterials Science (miscellaneous)$$c2020$$dQ1
000094478 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/submittedVersion
000094478 700__ $$aSreedhara, M.B.
000094478 700__ $$aSerra, M.
000094478 700__ $$aSinha, S.S.
000094478 700__ $$aPopovitz-Biro, R.
000094478 700__ $$aPinkas, I.
000094478 700__ $$aEnyashin, A.N.
000094478 700__ $$aTenne, R.
000094478 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, R.$$uUniversidad de Zaragoza
000094478 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000094478 773__ $$g14, 5 (2020), 5445-5458$$pACS Nano$$tACS nano$$x1936-0851
000094478 8564_ $$s1807320$$uhttps://zaguan.unizar.es/record/94478/files/texto_completo.pdf$$yPreprint
000094478 8564_ $$s159252$$uhttps://zaguan.unizar.es/record/94478/files/texto_completo.jpg?subformat=icon$$xicon$$yPreprint
000094478 909CO $$ooai:zaguan.unizar.es:94478$$particulos$$pdriver
000094478 951__ $$a2021-09-02-10:11:30
000094478 980__ $$aARTICLE