000095072 001__ 95072
000095072 005__ 20210902121754.0
000095072 0247_ $$2doi$$a10.1002/adsc.202000514
000095072 0248_ $$2sideral$$a118726
000095072 037__ $$aART-2020-118726
000095072 041__ $$aeng
000095072 100__ $$aNolla-Saltiel, R.
000095072 245__ $$aHydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex
000095072 260__ $$c2020
000095072 5060_ $$aAccess copy available to the general public$$fUnrestricted
000095072 5203_ $$aHerein we report the synthesis of three heteroleptic first-row transition metal(II) complexes containing carbazolido NNN pincer ligands and conversion to the corresponding metal(I)-carbonyl complexes via a reductive carbonylation route. These complexes are precatalysts for the hydrophosphination of activated alkenes, affording a cobalt-catalysed hydrophosphination process that solely and selectively yields the ß addition (anti-Markovnikov) product. The scope of this transformation has been investigated using a variety of activated alkenes. Isolation and characterisation of substrate-coordinated intermediates reveal available coordination sites, which provide insight into the proposed catalytic cycle.
000095072 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000095072 590__ $$a5.837$$b2020
000095072 591__ $$aCHEMISTRY, ORGANIC$$b7 / 57 = 0.123$$c2020$$dQ1$$eT1
000095072 591__ $$aCHEMISTRY, APPLIED$$b11 / 74 = 0.149$$c2020$$dQ1$$eT1
000095072 592__ $$a1.54$$b2020
000095072 593__ $$aOrganic Chemistry$$c2020$$dQ1
000095072 593__ $$aCatalysis$$c2020$$dQ1
000095072 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000095072 700__ $$0(orcid)0000-0003-1115-6759$$aGeer, A.M.
000095072 700__ $$aTaylor, L.J.
000095072 700__ $$aChurchill, O.
000095072 700__ $$aDavies, E.S.
000095072 700__ $$aLewis, W.
000095072 700__ $$aBlake, A.J.
000095072 700__ $$aKays, D.L.
000095072 773__ $$g362, 15 (2020), 3148-3157$$pAdv. synth. catal.$$tAdvanced Synthesis and Catalysis$$x1615-4150
000095072 8564_ $$s4785764$$uhttps://zaguan.unizar.es/record/95072/files/texto_completo.pdf$$yVersión publicada
000095072 8564_ $$s562331$$uhttps://zaguan.unizar.es/record/95072/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000095072 909CO $$ooai:zaguan.unizar.es:95072$$particulos$$pdriver
000095072 951__ $$a2021-09-02-09:50:50
000095072 980__ $$aARTICLE