95072 20210902121754.0 doi 10.1002/adsc.202000514 sideral 118726 ART-2020-118726 eng Nolla-Saltiel, R. Hydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex 2020 Access copy available to the general public Unrestricted Herein we report the synthesis of three heteroleptic first-row transition metal(II) complexes containing carbazolido NNN pincer ligands and conversion to the corresponding metal(I)-carbonyl complexes via a reductive carbonylation route. These complexes are precatalysts for the hydrophosphination of activated alkenes, affording a cobalt-catalysed hydrophosphination process that solely and selectively yields the ß addition (anti-Markovnikov) product. The scope of this transformation has been investigated using a variety of activated alkenes. Isolation and characterisation of substrate-coordinated intermediates reveal available coordination sites, which provide insight into the proposed catalytic cycle. info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 5.837 2020 CHEMISTRY, ORGANIC 7 / 57 = 0.123 2020 Q1 T1 CHEMISTRY, APPLIED 11 / 74 = 0.149 2020 Q1 T1 1.54 2020 Organic Chemistry 2020 Q1 Catalysis 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Geer, A.M. (orcid)0000-0003-1115-6759 Taylor, L.J. Churchill, O. Davies, E.S. Lewis, W. Blake, A.J. Kays, D.L. 362, 15 (2020), 3148-3157 Adv. synth. catal. Advanced Synthesis and Catalysis 1615-4150 4785764 http://zaguan.unizar.es/record/95072/files/texto_completo.pdf Versión publicada 562331 http://zaguan.unizar.es/record/95072/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:95072 articulos driver 2021-09-02-09:50:50 ARTICLE