000095594 001__ 95594
000095594 005__ 20241108104651.0
000095594 0247_ $$2doi$$a10.1021/jacs.0c02399
000095594 0248_ $$2sideral$$a119912
000095594 037__ $$aART-2020-119912
000095594 041__ $$aeng
000095594 100__ $$aFaghani, A.
000095594 245__ $$aMetal-Assisted and Solvent-Mediated Synthesis of Two-Dimensional Triazine Structures on Gram Scale
000095594 260__ $$c2020
000095594 5060_ $$aAccess copy available to the general public$$fUnrestricted
000095594 5203_ $$aCovalent triazine frameworks are an emerging material class that have shown promising performance for a range of applications. In this work, we report on a metal-assisted and solvent-mediated reaction between calcium carbide and cyanuric chloride, as cheap and commercially available precursors, to synthesize two-dimensional triazine structures (2DTSs). The reaction between the solvent, dimethylformamide, and cyanuric chloride was promoted by calcium carbide and resulted in dimethylamino-s-triazine intermediates, which in turn undergo nucleophilic substitutions. This reaction was directed into two dimensions by calcium ions derived from calcium carbide and induced the formation of 2DTSs. The role of calcium ions to direct the two-dimensionality of the final structure was simulated using DFT and further proven by synthesizing molecular intermediates. The water content of the reaction medium was found to be a crucial factor that affected the structure of the products dramatically. While 2DTSs were obtained under anhydrous conditions, a mixture of graphitic material/2DTSs or only graphitic material (GM) was obtained in aqueous solutions. Due to the straightforward and gram-scale synthesis of 2DTSs, as well as their photothermal and photodynamic properties, they are promising materials for a wide range of future applications, including bacteria and virus incapacitation.
000095594 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/MAT2016-79776-P$$9info:eu-repo/grantAgreement/ES/MICINN/GATES-PCI2018-093137$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 881603-GrapheneCore3$$9info:eu-repo/grantAgreement/EC/H2020/881603/EU/Graphene Flagship Core Project 3/GrapheneCore3$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 823717-ESTEEM3$$9info:eu-repo/grantAgreement/EC/H2020/823717/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM3$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 785219-GrapheneCore2$$9info:eu-repo/grantAgreement/EC/H2020/785219/EU/Graphene Flagship Core Project 2/GrapheneCore2
000095594 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000095594 590__ $$a15.419$$b2020
000095594 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b15 / 178 = 0.084$$c2020$$dQ1$$eT1
000095594 592__ $$a7.115$$b2020
000095594 593__ $$aBiochemistry$$c2020$$dQ1
000095594 593__ $$aColloid and Surface Chemistry$$c2020$$dQ1
000095594 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000095594 593__ $$aCatalysis$$c2020$$dQ1
000095594 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/submittedVersion
000095594 700__ $$aGholami, M.F.
000095594 700__ $$aTrunk, M.
000095594 700__ $$aMüller, J.
000095594 700__ $$aPachfule, P.
000095594 700__ $$aVogl, S.
000095594 700__ $$aDonskyi, I.
000095594 700__ $$aLi, M.
000095594 700__ $$aNickl, P.
000095594 700__ $$aShao, J.
000095594 700__ $$aHuang, M.R.S.
000095594 700__ $$aUnger, W.E.S.
000095594 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, R.$$uUniversidad de Zaragoza
000095594 700__ $$aKoch, C.T.
000095594 700__ $$aPaulus, B.
000095594 700__ $$aRabe, J.P.
000095594 700__ $$aThomas, A.
000095594 700__ $$aHaag, R.
000095594 700__ $$aAdeli, M.
000095594 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000095594 773__ $$g142, 30 (2020), 12976-12986$$pJ. Am. Chem. Soc.$$tJournal of the American Chemical Society$$x0002-7863
000095594 8564_ $$s1008497$$uhttps://zaguan.unizar.es/record/95594/files/texto_completo.pdf$$yPostprint
000095594 8564_ $$s366029$$uhttps://zaguan.unizar.es/record/95594/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000095594 909CO $$ooai:zaguan.unizar.es:95594$$particulos$$pdriver
000095594 951__ $$a2024-11-08-10:44:44
000095594 980__ $$aARTICLE