000095637 001__ 95637
000095637 005__ 20220426091132.0
000095637 0247_ $$2doi$$a10.1002/cplu.202000473
000095637 0248_ $$2sideral$$a119817
000095637 037__ $$aART-2020-119817
000095637 041__ $$aeng
000095637 100__ $$aAlegre-Requena, J.V.
000095637 245__ $$aSelf-Assembly of Hollow Organic Nanotubes Driven by Arene Regioisomerism
000095637 260__ $$c2020
000095637 5060_ $$aAccess copy available to the general public$$fUnrestricted
000095637 5203_ $$aArene regioisomerism in low-molecular-weight gelators can be exploited as a tool to modulate the micro-structures of the corresponding xerogel networks by using the three different possible substitution patterns ortho, meta and para. This aromatic regioisomer-driven strategy has been used with a cholesterol-based gelator to prepare hollow self-assembled organic nanotubes (S-ONTs) with inside and outside diameters of ca. 35 and 140 nm, respectively. Electron microscopy imaging and theoretical calculations were employed to rationalize the formation mechanism of these S-ONTs. From the three possible regioisomers, only the ortho-disubstituted cholesteryl-based gelator showed the optimal angle and distance between substituents to afford the formation of the cyclic assemblies required for nanotube growth by assembling 30–40 units of the gelator. This study opens fascinating opportunities to expand the synthesis of controllable and unique microstructures by modulating geometrical parameters through aromatic regioisomers.
000095637 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/E07-20R$$9info:eu-repo/grantAgreement/ES/MCIU/RED2018-102471-T$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2017-88091-P
000095637 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000095637 590__ $$a2.863$$b2020
000095637 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b95 / 178 = 0.534$$c2020$$dQ3$$eT2
000095637 592__ $$a0.801$$b2020
000095637 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000095637 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000095637 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, Raquel$$uUniversidad de Zaragoza
000095637 700__ $$aDíaz Díaz, D.
000095637 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000095637 773__ $$g85, 11 (2020), 2372-2375$$pChemPlusChem$$tChemPlusChem$$x2192-6506
000095637 8564_ $$s1081614$$uhttps://zaguan.unizar.es/record/95637/files/texto_completo.pdf$$yVersión publicada
000095637 8564_ $$s72193$$uhttps://zaguan.unizar.es/record/95637/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000095637 909CO $$ooai:zaguan.unizar.es:95637$$particulos$$pdriver
000095637 951__ $$a2022-04-26-08:52:07
000095637 980__ $$aARTICLE