000095698 001__ 95698 000095698 005__ 20230622083315.0 000095698 0247_ $$2doi$$a10.1021/acsmaterialslett.0c00108 000095698 0248_ $$2sideral$$a118909 000095698 037__ $$aART-2020-118909 000095698 041__ $$aeng 000095698 100__ $$aSideri, IK 000095698 245__ $$aCovalently Functionalized MoS2 with Dithiolenes 000095698 260__ $$c2020 000095698 5060_ $$aAccess copy available to the general public$$fUnrestricted 000095698 5203_ $$aAdvances are required to develop functionalization routes for MoS2, in both the metallic 1T and semi-conducting 2H phase, that will not only enable their easier manipulation and handling in liquid media but also enhance their applicability in diverse technological fields. Herein, we report an original functionalization methodology for covalently incorporating dithiolene units at the periphery of exfoliated 1T-and 2H-MoS2 sheets, by employing a bis(thiolate) salt as a ligand in a green and facile protocol. Extensive characterization of the covalently functionalized materials is presented, along with a pathway for the a la carte chemical manipulation of MoS2. Markedly, the reported methodology may be applied for modifying other transition metal dichalcogenides. 000095698 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-79776-P$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 881603- GrapheneCore3$$9info:eu-repo/grantAgreement/EC/H2020/881603/EU/Graphene Flagship Core Project 3/ GrapheneCore3$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 823717-ESTEEM3$$9info:eu-repo/grantAgreement/EC/H2020/823717/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM3$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 785219-GrapheneCore2$$9info:eu-repo/grantAgreement/EC/H2020/785219/EU/Graphene Flagship Core Project 2/GrapheneCore2$$9info:eu-repo/grantAgreement/ES/DGA/E13-17R 000095698 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/ 000095698 590__ $$a8.312$$b2020 000095698 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b50 / 333 = 0.15$$c2020$$dQ1$$eT1 000095698 592__ $$a3.661$$b2020 000095698 593__ $$aBiomedical Engineering$$c2020$$dQ1 000095698 593__ $$aMaterials Science (miscellaneous)$$c2020$$dQ1 000095698 593__ $$aChemical Engineering (miscellaneous)$$c2020$$dQ1 000095698 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/submittedVersion 000095698 700__ $$0(orcid)0000-0002-2071-9093$$aArenal, R$$uUniversidad de Zaragoza 000095698 700__ $$aTagmatarchis, N 000095698 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada 000095698 773__ $$g2, 7 (2020), 832-837$$tACS Materials Letters$$x2639-4979 000095698 8564_ $$s445324$$uhttps://zaguan.unizar.es/record/95698/files/texto_completo.pdf$$yPreprint 000095698 8564_ $$s611051$$uhttps://zaguan.unizar.es/record/95698/files/texto_completo.jpg?subformat=icon$$xicon$$yPreprint 000095698 909CO $$ooai:zaguan.unizar.es:95698$$particulos$$pdriver 000095698 951__ $$a2023-06-21-15:01:44 000095698 980__ $$aARTICLE