doi:10.1039/c9cy02128kengSorribes, IvánLemos, Samantha CSMartín, SantiagoMayoral, ÁlvaroLima, Renata CAndres, JuanPalladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcoholsART-2019-114681Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C-N bond cleavage methodology is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance.2019http://zaguan.unizar.es/record/9608510.1039/c9cy02128khttp://zaguan.unizar.es/record/96085oai:zaguan.unizar.es:96085info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragóninfo:eu-repo/grantAgreement/ES/DGA-FEDER/E31-17Rinfo:eu-repo/grantAgreement/ES/MICINN/Juan de la Cierva Program-IJCI-2016-30590info:eu-repo/grantAgreement/ES/MINECO-FEDER/PGC2018-094417-B-I00Catalysis Science and Technology 9, 24 (2019), 6965-6976All rights reservedhttp://www.europeana.eu/rights/rr-f/info:eu-repo/semantics/openAccess