000097054 001__ 97054 000097054 005__ 20210902121611.0 000097054 0247_ $$2doi$$a10.1002/chem.201904141 000097054 0248_ $$2sideral$$a115746 000097054 037__ $$aART-2020-115746 000097054 041__ $$aeng 000097054 100__ $$0(orcid)0000-0003-3691-3437$$aAndrés, Miguel A.$$uUniversidad de Zaragoza 000097054 245__ $$aUltrathin Films of Porous Metal–Organic Polyhedra for Gas Separation 000097054 260__ $$c2020 000097054 5060_ $$aAccess copy available to the general public$$fUnrestricted 000097054 5203_ $$aUltrathin films of a robust RhII-based porous metal–organic polyhedra (MOP) have been obtained. Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmission electron microscopy and atomic force microscopy. As a proof of concept, the gas separation performance of MOP-supported membranes has also been evaluated. Selective MOP ultrathin films (thickness ca. 60 nm) exhibit remarkable CO2 permeance and CO2/N2 selectivity, demonstrating the great combined potential of MOP and Langmuir-based techniques in separation technologies. 000097054 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E31-17R$$9info:eu-repo/grantAgreement/ES/DGA/T43-17R$$9info:eu-repo/grantAgreement/EC/FP7/615954/EU/Multifunctional micro- and nanostructures assembled from nanoscale metal-organic frameworks and inorganic nanoparticles/InanoMOF$$9info:eu-repo/grantAgreement/ES/MEC/FPU2014$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-095622-B-100$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-77290-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2017-86826-R 000097054 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000097054 590__ $$a5.236$$b2020 000097054 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b52 / 178 = 0.292$$c2020$$dQ2$$eT1 000097054 592__ $$a1.687$$b2020 000097054 593__ $$aCatalysis$$c2020$$dQ1 000097054 593__ $$aOrganic Chemistry$$c2020$$dQ1 000097054 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1 000097054 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000097054 700__ $$aCarné-Sánchez, Arnau 000097054 700__ $$0(orcid)0000-0001-6627-0079$$aSánchez-Laínez, Javier 000097054 700__ $$0(orcid)0000-0003-2095-5843$$aRoubeau, Olivier$$uUniversidad de Zaragoza 000097054 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza 000097054 700__ $$aMaspoch, Daniel 000097054 700__ $$0(orcid)0000-0002-3492-6456$$aGascón, Ignacio$$uUniversidad de Zaragoza 000097054 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química 000097054 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física 000097054 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada 000097054 773__ $$g26, 1 (2020), 143-147$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539 000097054 8564_ $$s398054$$uhttps://zaguan.unizar.es/record/97054/files/texto_completo.pdf$$yPostprint 000097054 8564_ $$s649445$$uhttps://zaguan.unizar.es/record/97054/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000097054 909CO $$ooai:zaguan.unizar.es:97054$$particulos$$pdriver 000097054 951__ $$a2021-09-02-08:40:56 000097054 980__ $$aARTICLE