97054 20210902121611.0 doi 10.1002/chem.201904141 sideral 115746 ART-2020-115746 eng Andrés, Miguel A. Universidad de Zaragoza (orcid)0000-0003-3691-3437 Ultrathin Films of Porous Metal–Organic Polyhedra for Gas Separation 2020 Access copy available to the general public Unrestricted Ultrathin films of a robust RhII-based porous metal–organic polyhedra (MOP) have been obtained. Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmission electron microscopy and atomic force microscopy. As a proof of concept, the gas separation performance of MOP-supported membranes has also been evaluated. Selective MOP ultrathin films (thickness ca. 60 nm) exhibit remarkable CO2 permeance and CO2/N2 selectivity, demonstrating the great combined potential of MOP and Langmuir-based techniques in separation technologies. info:eu-repo/grantAgreement/ES/DGA/E31-17R info:eu-repo/grantAgreement/ES/DGA/T43-17R info:eu-repo/grantAgreement/EC/FP7/615954/EU/Multifunctional micro- and nanostructures assembled from nanoscale metal-organic frameworks and inorganic nanoparticles/InanoMOF info:eu-repo/grantAgreement/ES/MEC/FPU2014 info:eu-repo/grantAgreement/ES/MICINN/RTI2018-095622-B-100 info:eu-repo/grantAgreement/ES/MINECO/MAT2016-77290-R info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R info:eu-repo/grantAgreement/ES/MINECO/MAT2017-86826-R info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 5.236 2020 CHEMISTRY, MULTIDISCIPLINARY 52 / 178 = 0.292 2020 Q2 T1 1.687 2020 Catalysis 2020 Q1 Organic Chemistry 2020 Q1 Chemistry (miscellaneous) 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Carné-Sánchez, Arnau Sánchez-Laínez, Javier (orcid)0000-0001-6627-0079 Roubeau, Olivier Universidad de Zaragoza (orcid)0000-0003-2095-5843 Coronas, Joaquín Universidad de Zaragoza (orcid)0000-0003-1512-4500 Maspoch, Daniel Gascón, Ignacio Universidad de Zaragoza (orcid)0000-0002-3492-6456 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 2003 395 Universidad de Zaragoza Dpto. Física Materia Condensa. Área Física Materia Condensada 26, 1 (2020), 143-147 Chemistry (Weinh.) Chemistry - A European Journal 0947-6539 398054 http://zaguan.unizar.es/record/97054/files/texto_completo.pdf Postprint 649445 http://zaguan.unizar.es/record/97054/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:97054 articulos driver 2021-09-02-08:40:56 ARTICLE