Ferrocenyl gold complexes as efficient catalysts

Pérez-Sánchez, J. C. ; Pérez Herrera, R. ; Gimeno, M. C.

Resumen: More than half a century after the discovery of the ferrocene structure in 1951, it remains as a suitable building block in many research areas, including catalysis with the development of key chiral catalysts. On the other hand, gold-mediated catalysis has been raised in recent years, allowing the creation of a great variety of C-C bonds and C-heteroatom bonds. In this context, this review covers the recent advances made with the combination of these two iconic figures in the organometallic chemistry field, since the first gold catalyzed reaction using a ferrocene ligand reported in 1986. The combination of the excellent properties and versatility of this metallocene, has allowed the obtainment of a plethora of ligands for metal catalysis, although their use joined to gold catalysis is still scarcely explored.

Idioma: Inglés

DOI: 10.1002/ejic.202101067

Año: 2022

Publicado en: European Journal of Inorganic Chemistry 12 (2022), e202101067 [13 pp.]
ISSN: 1434-1948

Factor impacto JCR: 2.3 (2022)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 21 / 42 = 0.5 (2022) - Q2 - T2

Factor impacto CITESCORE: 4.4 - Chemistry (Q2)

Factor impacto SCIMAGO: 0.527 - Inorganic Chemistry (Q2)

Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E07-20R
Financiación: info:eu-repo/grantAgreement/ES/MCIU/PID2019-104379RB-C21
Financiación: info:eu-repo/grantAgreement/ES/MCIN/AEI/10.13039/501100011033

Tipo y forma: Review (Published version)