Green supported liquid membranes: The permeability activity-based linear operation (PABLO) method
López-Porfiri, P. ; González-Miquel, M. ; Gorgojo Alonso, P. (Universidad de Zaragoza)
Resumen: Supported liquid membranes (SLMs) containing novel green solvents are proposed as a sustainable alternative separation process in the recovery of biomolecules. In this work, succinic acid has been successfully extracted from model fermentation broths through a stripping phase-facilitated transport mechanism with four different green supported liquid membranes: two eutectic solvents (DL-menthol:OctA and N4444Cl:OctA), the bio-based solvent eucalyptol and the ionic liquid C4pyrr]Tf2N]. A permeability activity-based model that takes into account for the first time solute-phase affinities has been developed using the quantum chemical COSMO-RS method; the model corrects the mass transfer driving force and allows extraction predictions beyond the concentration equilibrium. The best recovery has been achieved experimentally for the eucalyptol-based SLM (concentration factor of 1.4) using an alkaline aqueous solution (0.5 M NaOH) as the stripping phase. A countercurrent cascade extraction process design is proposed, and a graphical method to determine the stage number, interstage concentrations as well as mass transfer area requirements is presented. This new tool, the Permeability Activity-Based Linear Operation (PABLO) method, will substantially enhance the process design of SLMs technology for the biorefinery industry.
Idioma: Inglés
DOI: 10.1016/j.cej.2022.137253
Año: 2022
Publicado en: Chemical Engineering Journal 446, 3 (2022), 137253 [11 pp]
ISSN: 1385-8947
Factor impacto JCR: 15.1 (2022)
Categ. JCR: ENGINEERING, ENVIRONMENTAL rank: 3 / 55 = 0.055 (2022) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 5 / 141 = 0.035 (2022) - Q1 - T1
Factor impacto CITESCORE: 21.5 - Engineering (Q1) - Chemistry (Q1) - Chemical Engineering (Q1) - Environmental Science (Q1)
Factor impacto SCIMAGO: 2.803 - Chemical Engineering (miscellaneous) (Q1) - Industrial and Manufacturing Engineering (Q1) - Environmental Chemistry (Q1) - Chemistry (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC2019-027060-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
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Idioma: Inglés
DOI: 10.1016/j.cej.2022.137253
Año: 2022
Publicado en: Chemical Engineering Journal 446, 3 (2022), 137253 [11 pp]
ISSN: 1385-8947
Factor impacto JCR: 15.1 (2022)
Categ. JCR: ENGINEERING, ENVIRONMENTAL rank: 3 / 55 = 0.055 (2022) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 5 / 141 = 0.035 (2022) - Q1 - T1
Factor impacto CITESCORE: 21.5 - Engineering (Q1) - Chemistry (Q1) - Chemical Engineering (Q1) - Environmental Science (Q1)
Factor impacto SCIMAGO: 2.803 - Chemical Engineering (miscellaneous) (Q1) - Industrial and Manufacturing Engineering (Q1) - Environmental Chemistry (Q1) - Chemistry (miscellaneous) (Q1)
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC2019-027060-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2024-03-18-16:13:32)
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Record created 2022-09-08, last modified 2024-03-19