Directionally solidified cobalt-doped MgO-MgAl2O4 eutectic composites for selective emitters
Resumen: Cobalt-doped MgO-MgAl2O4 eutectic composites were explored for their use as selective emitters for thermophotovoltaic devices. Eutectic ceramic rods with different cobalt content were directionally solidified by using the laser floating zone technique at two processing rates to obtain microstructures with different domain sizes. Thermal emission between 1000 °C and 1500 °C and optical properties (reflectance and transmittance) at room temperature were measured in the Co-doped composites and the effect on microstructure and cobalt content was investigated. Thermal emission consisted of an intense broad band at about 1.67 µm matching with the bandgap of the InGaAs cell. The emission was ascribed to the de-excitation from the 4T1(F) multiplet to the 4A2(F) ground state of the thermally excited Co ions located in the tetrahedral sites of the MgAl2O4 phase. The selectivity of the thermal emission showed a decrease with the cobalt content due to the enhancement of other electronic transitions, which leads to keeping the cobalt content in these composites at low levels (<0.15% at Co) for their use as selective emitters.
Idioma: Inglés
DOI: 10.3390/app122010254
Año: 2022
Publicado en: Applied Sciences (Switzerland) 12, 20 (2022), 10254
ISSN: 2076-3417

Factor impacto JCR: 2.7 (2022)
Categ. JCR: PHYSICS, APPLIED rank: 78 / 160 = 0.488 (2022) - Q2 - T2
Categ. JCR: ENGINEERING, MULTIDISCIPLINARY rank: 42 / 90 = 0.467 (2022) - Q2 - T2
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 100 / 178 = 0.562 (2022) - Q3 - T2
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 208 / 343 = 0.606 (2022) - Q3 - T2

Factor impacto CITESCORE: 4.5 - Engineering (Q2) - Materials Science (Q2) - Chemical Engineering (Q2) - Computer Science (Q2) - Physics and Astronomy (Q2)

Factor impacto SCIMAGO: 0.492 - Fluid Flow and Transfer Processes (Q2) - Materials Science (miscellaneous) (Q2) - Engineering (miscellaneous) (Q2) - Instrumentation (Q2) - Process Chemistry and Technology (Q3) - Computer Science Applications (Q3)

Tipo y forma: Artículo (Versión definitiva)
Área (Departamento): Área Cienc.Mater. Ingen.Metal. (Dpto. Ciencia Tecnol.Mater.Fl.)

Creative Commons Debe reconocer adecuadamente la autoría, proporcionar un enlace a la licencia e indicar si se han realizado cambios. Puede hacerlo de cualquier manera razonable, pero no de una manera que sugiera que tiene el apoyo del licenciador o lo recibe por el uso que hace.


Exportado de SIDERAL (2024-03-18-16:36:38)


Visitas y descargas

Este artículo se encuentra en las siguientes colecciones:
Artículos



 Registro creado el 2022-11-15, última modificación el 2024-03-19


Versión publicada:
 PDF
Valore este documento:

Rate this document:
1
2
3
 
(Sin ninguna reseña)