Directionally solidified cobalt-doped MgO-MgAl2O4 eutectic composites for selective emitters

Merino, Rosa I. ; Oliete, Patricia B. (Universidad de Zaragoza) ; Moshtaghion, Bibi Malmal ; Sola, Daniel ; Peña, José I. (Universidad de Zaragoza)

Resumen: Cobalt-doped MgO-MgAl2O4 eutectic composites were explored for their use as selective emitters for thermophotovoltaic devices. Eutectic ceramic rods with different cobalt content were directionally solidified by using the laser floating zone technique at two processing rates to obtain microstructures with different domain sizes. Thermal emission between 1000 °C and 1500 °C and optical properties (reflectance and transmittance) at room temperature were measured in the Co-doped composites and the effect on microstructure and cobalt content was investigated. Thermal emission consisted of an intense broad band at about 1.67 µm matching with the bandgap of the InGaAs cell. The emission was ascribed to the de-excitation from the 4T1(F) multiplet to the 4A2(F) ground state of the thermally excited Co ions located in the tetrahedral sites of the MgAl2O4 phase. The selectivity of the thermal emission showed a decrease with the cobalt content due to the enhancement of other electronic transitions, which leads to keeping the cobalt content in these composites at low levels (<0.15% at Co) for their use as selective emitters.

Idioma: Inglés

DOI: 10.3390/app122010254

Año: 2022

Publicado en: Applied Sciences (Switzerland) 12, 20 (2022), 10254
ISSN: 2076-3417

Factor impacto JCR: 2.7 (2022)

Categ. JCR: PHYSICS, APPLIED rank: 78 / 160 = 0.488 (2022) - Q2 - T2
Categ. JCR: ENGINEERING, MULTIDISCIPLINARY rank: 42 / 90 = 0.467 (2022) - Q2 - T2
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 100 / 178 = 0.562 (2022) - Q3 - T2
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 208 / 343 = 0.606 (2022) - Q3 - T2

Factor impacto CITESCORE: 4.5 - Engineering (Q2) - Materials Science (Q2) - Chemical Engineering (Q2) - Computer Science (Q2) - Physics and Astronomy (Q2)

Factor impacto SCIMAGO: 0.492 - Fluid Flow and Transfer Processes (Q2) - Materials Science (miscellaneous) (Q2) - Engineering (miscellaneous) (Q2) - Instrumentation (Q2) - Process Chemistry and Technology (Q3) - Computer Science Applications (Q3)

Tipo y forma: Article (Published version)

Área (Departamento): Área Cienc.Mater. Ingen.Metal. (Dpto. Ciencia Tecnol.Mater.Fl.)