Conversion of NH3 and NH3-NO mixtures in a CO2 atmosphere. A parametric study

Alzueta, María U. (Universidad de Zaragoza) ; Giménez-López, Jorge ; Mercader, Víctor D. (Universidad de Zaragoza) ; Bilbao, Rafael (Universidad de Zaragoza)

Resumen: The present work addresses the oxidation of ammonia and ammonia-nitric oxide mixtures in a CO2 atmosphere, characteristic of oxy-fuel processes and/or biogas combustion, from both experimental and kinetic modelling points of view. A parametric study of NH3 and NH3/NO mixtures oxidation is carried out, evaluating the influence of the temperature (700–1500 K), stoichiometry (from pyrolysis, λ = 0, to significantly oxidizing conditions, λ = 3.3), gas residence time (low values, 195/T(K) s and high values, 3100/T(K) s) and NH3/NO ratio (0.5–2.2), at atmospheric pressure under well-controlled laboratory conditions using two tubular flow reactor setups. Experimental results have been simulated with an updated literature reaction mechanism, which has been used to interpret the experimental observations.

Idioma: Inglés

DOI: 10.1016/j.fuel.2022.125133

Año: 2022

Publicado en: Fuel 327 (2022), 125133 [8 pp.]
ISSN: 0016-2361

Factor impacto JCR: 7.4 (2022)

Categ. JCR: ENGINEERING, CHEMICAL rank: 19 / 141 = 0.135 (2022) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 32 / 119 = 0.269 (2022) - Q2 - T1

Factor impacto CITESCORE: 12.2 - Energy (Q1) - Chemistry (Q1) - Chemical Engineering (Q1)

Factor impacto SCIMAGO: 1.38 - Chemical Engineering (miscellaneous) (Q1) - Organic Chemistry (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN-AEI-FEDER/RTI2018-098856-B-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-124032OB-I00

Tipo y forma: Article (Published version)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)