Effect of Ethylene Glycol: Citric Acid Molar Ratio and pH on the Morphology, Vibrational, Optical and Electronic Properties of TiO2 and CuO Powders Synthesized by Pechini Method

Vargas-Urbano, Mónica A. ; Marín, Lorena ; Castillo, Winny Mónica ; Rodríguez, Luis Alfredo ; Magén, César (Universidad de Zaragoza) ; Manotas-Albor, Milton ; Diosa, Jesús Evelio ; Gross, Katherine

Resumen: High-purity TiO2 and CuO powders were synthesized by the Pechini method, an inexpensive and easy-to-implement procedure to synthetize metal oxides. The variables of synthesis were the ethylene glycol:citric acid molar ratio and the pH. High reproducibility of the anatase and tenorite phase was obtained for all synthesis routes. The degree of purity of the powders was confirmed by XRD, FTIR, UV-Vis absorption and XPS spectra. SEM and TEM images revealed the powders are composed of micrometer grains that can have a spherical shape (only in the TiO2) or formed by a non-compacted nanocrystalline conglomerate. FTIR spectra only displayed vibrational modes associating TiO2 and CuO with nanoparticle behavior. UV-Vis absorption spectra revealed the values of maximum absorbance percentage of both systems are reached in the ultraviolet region, with percentages above 83% throughout the entire visible light spectrum for the CuO system, a relevant result for solar cell applications. Finally, XPS experiments allow the observation of the valence bands and the calculation of the energy bands of all oxides.

Idioma: Inglés

DOI: 10.3390/ma15155266

Año: 2022

Publicado en: Materials 15, 15 (2022), 5266 [16 pp.]
ISSN: 1996-1944

Factor impacto JCR: 3.4 (2022)

Categ. JCR: METALLURGY & METALLURGICAL ENGINEERING rank: 20 / 79 = 0.253 (2022) - Q2 - T1
Categ. JCR: PHYSICS, APPLIED rank: 57 / 160 = 0.356 (2022) - Q2 - T2
Categ. JCR: PHYSICS, CONDENSED MATTER rank: 29 / 67 = 0.433 (2022) - Q2 - T2
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 174 / 343 = 0.507 (2022) - Q3 - T2
Categ. JCR: CHEMISTRY, PHYSICAL rank: 84 / 161 = 0.522 (2022) - Q3 - T2

Factor impacto CITESCORE: 5.2 - Materials Science (Q2)

Factor impacto SCIMAGO: 0.563 - Materials Science (miscellaneous) (Q2) - Condensed Matter Physics (Q2)

Tipo y forma: Article (Published version)

Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)