Ultra-high performance liquid chromatography coupled to ion mobility quadrupole time-of-flight mass spectrometry for the identification of non-volatile compounds migrating from ´natural´ dishes

Wrona, Magdalena (Universidad de Zaragoza) ; Román, Ana ; Song, Xue-Chao ; Nerín, Cristina (Universidad de Zaragoza) ; Dreolin, Nicola ; Goshawk, Jeff ; Asensio, Esther (Universidad de Zaragoza)

Resumen: Although most new biomaterials for food industry applications are labelled ‘100% natural fabrication’ and ‘chemical-free’, certain compounds may migrate from those materials to the food, compromis- ing the organoleptic characteristics and safety of the product. In this work, the degree of compound migration from dishes made with four different biomaterials: bamboo, palm leaf, wood and wheat pulp was investigated. Migration tests were carried out using three food simulants, 10% ethanol (sim- ulant A), 3% acetic acid (simulant B), and 95% ethanol (simulant D2). Unequivocal identification of non-intentionally added substances (NIAS) is challenging even when using high-resolution mass spectrometry techniques however, a total of 25 different non-volatile compounds from the migration tests were identified and quantified using Ultra-high performance liquid chromatography coupled to ion mobility quadrupole time-of-flight mass spectrometry (UPLC-IMS-MS). In the bamboo samples three oligomers, cyclic diethylene glycol adipate, 3,6,9,16,19,22-hexaoxabicyclo[22.3.1]-octacosa-1(28),24,26- triene-2,10,15,23-tetrone and 1,4,7,14,17,20-hexaoxacyclohexacosane-8,13,21,26-tetrone exceeded the specified limits of migration.

Idioma: Inglés

DOI: 10.1016/j.chroma.2023.463836

Año: 2023

Publicado en: Journal of Chromatography A 1691 (2023), 463836 [11 pp.]
ISSN: 0021-9673

Factor impacto JCR: 3.8 (2023)

Categ. JCR: CHEMISTRY, ANALYTICAL rank: 26 / 106 = 0.245 (2023) - Q1 - T1
Categ. JCR: BIOCHEMICAL RESEARCH METHODS rank: 15 / 85 = 0.176 (2023) - Q1 - T1

Factor impacto CITESCORE: 7.9 - Biochemistry (Q1) - Organic Chemistry (Q1) - Analytical Chemistry (Q1)

Factor impacto SCIMAGO: 0.717 - Analytical Chemistry (Q2) - Organic Chemistry (Q2) - Medicine (miscellaneous) (Q2) - Biochemistry (Q2)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/T53-20R

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Química Analítica (Dpto. Química Analítica)