000123955 001__ 123955
000123955 005__ 20240319081025.0
000123955 0247_ $$2doi$$a10.1039/d1dt04351j
000123955 0248_ $$2sideral$$a131060
000123955 037__ $$aART-2022-131060
000123955 041__ $$aeng
000123955 100__ $$aMartínez-Laguna, J.
000123955 245__ $$aGold nanoparticle-catalysed functionalization of carbon–hydrogen bonds by carbene transfer reactions
000123955 260__ $$c2022
000123955 5060_ $$aAccess copy available to the general public$$fUnrestricted
000123955 5203_ $$aGold nanoparticles stabilized by NHC ligands and supported onto reduced graphene oxide (rGO) catalyse the functionalization of cyclohexane and benzene C–H bonds upon insertion of carbene CHCO2Et (from N2[double bond, length as m-dash]CHCO2Et) groups. This is the first example in which such Csp3-H or Csp2-H bonds are functionalized with this strategy with nanoparticulated gold. This Au-NP@rGO material shows an exceptional activity, providing TON values 5–10 times higher than those already reported for molecular gold catalysts. Recyclability is also effective, reaching an accumulated TON value of 1400 after six consecutive uses.
000123955 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2020-113797RB-C21$$9info:eu-repo/grantAgreement/ES/DGA/E31-20R$$9info:eu-repo/grantAgreement/ES/MCIU/PID2019-105881RB-I00$$9info:eu-repo/grantAgreement/ES/MICIU/RTI2018-098237-B-C22
000123955 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000123955 590__ $$a4.0$$b2022
000123955 592__ $$a0.79$$b2022
000123955 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b7 / 42 = 0.167$$c2022$$dQ1$$eT1
000123955 593__ $$aInorganic Chemistry$$c2022$$dQ1
000123955 594__ $$a7.1$$b2022
000123955 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000123955 700__ $$aMollar-Cuni, A.
000123955 700__ $$aVentura-Espinosa, D.
000123955 700__ $$0(orcid)0000-0001-9193-3874$$aMartín, S.$$uUniversidad de Zaragoza
000123955 700__ $$aCaballero, A.
000123955 700__ $$aMata, J. A.
000123955 700__ $$aPérez, P. J.
000123955 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000123955 773__ $$g51, 13 (2022), 5250-5256$$pDalton Trans.$$tDalton Transactions$$x1477-9226
000123955 8564_ $$s1218524$$uhttps://zaguan.unizar.es/record/123955/files/texto_completo.pdf$$yPostprint
000123955 8564_ $$s2641817$$uhttps://zaguan.unizar.es/record/123955/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000123955 909CO $$ooai:zaguan.unizar.es:123955$$particulos$$pdriver
000123955 951__ $$a2024-03-18-16:38:34
000123955 980__ $$aARTICLE