On-surface synthesis of metal–organic frameworks: the critical role of the reaction conditions

Ruiz del Árbol, N. ; Sánchez-Sánchez, C. ; Martínez, J. I. ; Rodríguez, L. ; Serrate, D. ; Verdini, A. ; Floreano, L. ; Jacobson, P. ; Grill, L. ; Martín-Gago, J. A. ; López, M. F.

Resumen: Two different metal–organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally different emphasizing the critical role being played by the reaction conditions during their growth. This work highlights the importance of the balance between thermodynamics and kinetics in the final structure of surface-supported metal–organic networks.

Idioma: Inglés

DOI: 10.1039/D3CC00185G

Año: 2023

Publicado en: Chemical Communications 59, 20 (2023), 2954-2957
ISSN: 1359-7345

Factor impacto JCR: 4.3 (2023)

Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 72 / 231 = 0.312 (2023) - Q2 - T1

Factor impacto CITESCORE: 8.6 - Metals and Alloys (Q1) - Ceramics and Composites (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Electronic, Optical and Magnetic Materials (Q1) - Chemistry (all) (Q1) - Catalysis (Q2)

Factor impacto SCIMAGO: 1.133 - Electronic, Optical and Magnetic Materials (Q1) - Chemistry (miscellaneous) (Q1) - Ceramics and Composites (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Catalysis (Q2)

Financiación: info:eu-repo/grantAgreement/EUR/AEI/TED2021-129999B-C31
Financiación: info:eu-repo/grantAgreement/ES/MCIU/RYC2018-024364-I
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PLEC2021-007906/AEI/10.13039/501100011033
Financiación: info:eu-repo/grantAgreement/ES/MINECO/BES-2015-072642
Financiación: info:eu-repo/grantAgreement/ES/MINECO/PID2020-113142RB-C21

Tipo y forma: Congress (Published version)