Electrophilicity of neutral square-planar organosilver(III) compounds

Joven-Sancho, D. (Universidad de Zaragoza) ; Demonti, L. ; Martín, A. ; Saffon-Merceron, N. ; Nebra, N. ; Baya, M. (Universidad de Zaragoza) ; Menjón, B.

Resumen: Neutral Ag(III) complexes stabilised with just monodentate ligands are here unambiguously established. In a series of square-planar (CF3)3Ag(L) compounds with hard and soft Group 15 donor ligands, L, the metal center has been found to exhibit substantial acidity favouring apical coordination of an additional ligand under no coordination constraints.

Idioma: Inglés

DOI: 10.1039/d3cc00493g

Año: 2023

Publicado en: Chemical Communications 59, 28 (2023), 4166-4168
ISSN: 1359-7345

Factor impacto JCR: 4.3 (2023)

Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 72 / 231 = 0.312 (2023) - Q2 - T1

Factor impacto CITESCORE: 8.6 - Metals and Alloys (Q1) - Ceramics and Composites (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Electronic, Optical and Magnetic Materials (Q1) - Chemistry (all) (Q1) - Catalysis (Q2)

Factor impacto SCIMAGO: 1.133 - Electronic, Optical and Magnetic Materials (Q1) - Chemistry (miscellaneous) (Q1) - Ceramics and Composites (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Catalysis (Q2)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E17-20R
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-122869NB-I00
Financiación: info:eu-repo/grantAgreement/ES/MINECO/BES-2016-078732

Tipo y forma: Congress (Published version)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)