Evaluation of triphenylene-based MOF ultrathin films for lithium batteries
Ciria-Ramos, Isabel (Universidad de Zaragoza) ; Tejedor, Inés (Universidad de Zaragoza) ; Caparros, Lucía ; Doñagueda, Beatriz ; Lacruz, Oscar ; Urtizberea, Ainhoa (Universidad de Zaragoza) ; Roubeau, Olivier ; Gascón, Ignacio (Universidad de Zaragoza) ; Haro, Marta (Universidad de Zaragoza)
Resumen: Metal–organic frameworks (MOFs) are attractive candidates to meet the requirement of next-generation batteries, as functional materials with a high surface area, well-defined metal centers, and organic linkers through coordination bonds. Due to their great tunability, MOFs have been investigated as electrodes or electrolytes in lithium batteries and more recently as protective layers in anode-less batteries. Here, we synthesize a Ni3(HHTP)2 MOF directly at the air–liquid interface of a Langmuir trough and grow the electrode on a conductive substrate by the transference process. The characterization during Langmuir film formation shows that the addition of crystallization time during the compression process enhances the formation of 2D crystalline domains, as observed by in situ grazing-incidence X-ray diffraction. Next, the transferred Ni3(HHTP)2 ultrathin films were studied as working electrodes in Li batteries in a half-cell configuration and compared with bare copper. The results show that the Ni3(HHTP)2 film protects the Cu collector from oxidation, and the negative charge accumulates in the organic ligand during the lithiation process while NiII oxidizes to NiIII, unlike other triphenylene-based MOFs with CuII or CoII metal nodes. The galvanostatic plating–stripping cycles of the batteries show that the inclusion of the crystallization time improves the coulombic efficiency, especially significantly in the first cycles when the SEI is formed. This work shows the Langmuir technique as a useful tool to test MOF based materials for batteries with the advantages of using a low amount of raw materials and without the need to introduce additives (binder and electron conductor) in the electrodes. The electrochemical study of this type of electrode allows a first screening to synthesize electrodes based on MOFs and can be a tool for the preparation of protective coatings under optimized conditions.
Idioma: Inglés
DOI: 10.1039/d3dt00876b
Año: 2023
Publicado en: Dalton Transactions 52, 21 (2023), 7196-7207
ISSN: 1477-9226
Factor impacto JCR: 3.5 (2023)
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 13 / 44 = 0.295 (2023) - Q2 - T1
Factor impacto SCIMAGO: 0.697 - Inorganic Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E31-20R
Financiación: info:eu-repo/grantAgreement/ES/DGA/LMP71-21
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-105881RB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-108247RA-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-025222-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Química Física (Dpto. Química Física)
Área (Departamento): Área Cienc.Mater. Ingen.Metal. (Dpto. Ciencia Tecnol.Mater.Fl.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2024-07-19-18:43:32)
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Idioma: Inglés
DOI: 10.1039/d3dt00876b
Año: 2023
Publicado en: Dalton Transactions 52, 21 (2023), 7196-7207
ISSN: 1477-9226
Factor impacto JCR: 3.5 (2023)
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 13 / 44 = 0.295 (2023) - Q2 - T1
Factor impacto SCIMAGO: 0.697 - Inorganic Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/E31-20R
Financiación: info:eu-repo/grantAgreement/ES/DGA/LMP71-21
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-105881RB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2019-108247RA-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-025222-I
Tipo y forma: Article (Published version)
Área (Departamento): Área Química Física (Dpto. Química Física)
Área (Departamento): Área Cienc.Mater. Ingen.Metal. (Dpto. Ciencia Tecnol.Mater.Fl.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2024-07-19-18:43:32)
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Record created 2023-07-06, last modified 2024-07-20