000127648 001__ 127648
000127648 005__ 20241125101143.0
000127648 0247_ $$2doi$$a10.1016/j.cej.2023.144233
000127648 0248_ $$2sideral$$a134733
000127648 037__ $$aART-2023-134733
000127648 041__ $$aeng
000127648 100__ $$0(orcid)0000-0001-5002-7197$$aLuque-Alled, José Miguel$$uUniversidad de Zaragoza
000127648 245__ $$aOrganic solvent-free fabrication of thin film polyamide/zeolitic imidazolate framework membranes for removal of dyes from water
000127648 260__ $$c2023
000127648 5060_ $$aAccess copy available to the general public$$fUnrestricted
000127648 5203_ $$aThin film composite (TFC) polyamide (PA) membranes in combination with zeolitic imidazolate frameworks (ZIF), such as ZIF-8 and ZIF-93, have been fabricated using a novel approach based on vapor phase interfacial polymerization (VIP). These membranes have been investigated for nanofiltration (NF) of aqueous solutions of organic dyes, such as Rose Bengal (RB, 1017 Da), Sunset Yellow (SY, 452 Da) and Acridine Orange (AO, 265 Da). The preparation of the PA layer by VIP technique avoids the use of any organic solvent that is typically required in the conventional PA synthesis. Both ZIF-8 and ZIF-93 were initially synthesized using conventional procedures (methanol-based route) and incorporated to the PA layer in two different configurations: i) thin film nanocomposite with ZIF embedded within the PA film, and ii) bilayer membranes with a layer of ZIF between the support and the PA layer. The synthesis of ZIF-93 using a water-based route was developed for the bilayer configuration allowing for an organic solvent-free fabrication of PA/ZIF-93 bilayer VIP-TFC. These membranes showed the highest water permeances of 2.6, 3.4 and 2.2 L m-2h−1 bar−1 for RB, SY and AO, respectively. As compared to the control membrane VIP-TFC, this represents permeance increases of 69–117% and maintains high (greater than 99%) rejection of all the organic dyes. Membrane characterization demonstrated that the permeance enhancement for bilayer PA/ZIF-93 VIP-TFCs is related to an improved hydrophilicity, higher surface roughness and thinner selective layers. The prepared membranes demonstrated excellent cycle stability, maintaining their initial water permeance and dye rejection throughout 34 h of long-term operation, and being able to operate across the entire pH range studied (pH 3 to 9) without any detrimental effects on performance.
000127648 536__ $$9info:eu-repo/grantAgreement/ES/DGA/T68-23R$$9info:eu-repo/grantAgreement/ES/MCIN-AEI/PID2019-104009RB-I00-AEI-10.13039-501100011033$$9info:eu-repo/grantAgreement/ES/MICINN/RYC2019-027060-I
000127648 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000127648 590__ $$a13.4$$b2023
000127648 592__ $$a2.852$$b2023
000127648 591__ $$aENGINEERING, ENVIRONMENTAL$$b3 / 81 = 0.037$$c2023$$dQ1$$eT1
000127648 591__ $$aENGINEERING, CHEMICAL$$b7 / 170 = 0.041$$c2023$$dQ1$$eT1
000127648 593__ $$aEnvironmental Chemistry$$c2023$$dQ1
000127648 593__ $$aIndustrial and Manufacturing Engineering$$c2023$$dQ1
000127648 593__ $$aChemistry (miscellaneous)$$c2023$$dQ1
000127648 593__ $$aChemical Engineering (miscellaneous)$$c2023$$dQ1
000127648 594__ $$a21.7$$b2023
000127648 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000127648 700__ $$0(orcid)0000-0002-0990-0422$$aMartínez-Izquierdo, Lidia
000127648 700__ $$0(orcid)0000-0002-6905-714X$$aGorgojo, Patricia$$uUniversidad de Zaragoza
000127648 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, Carlos$$uUniversidad de Zaragoza
000127648 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, Joaquín$$uUniversidad de Zaragoza
000127648 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000127648 773__ $$g470 (2023), 144233 [17 pp.]$$pChem. eng. j.$$tChemical Engineering Journal$$x1385-8947
000127648 8564_ $$s17875070$$uhttps://zaguan.unizar.es/record/127648/files/texto_completo.pdf$$yVersión publicada
000127648 8564_ $$s2584977$$uhttps://zaguan.unizar.es/record/127648/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000127648 909CO $$ooai:zaguan.unizar.es:127648$$particulos$$pdriver
000127648 951__ $$a2024-11-22-12:03:17
000127648 980__ $$aARTICLE