Novel Ir1–xCoxO2 thin films: Growth and characterization
Financiación H2020 / H2020 Funds
Resumen: Ir1–xCoxO2 thin films have been prepared by reactive co–sputtering deposition at room temperature. Composition, structure, electronic properties and electric and magnetic behavior have been analyzed by different techniques including XRR, XRD, TEM microscopy, SQUID magnetometry, electrical resistivity and XAS spectroscopy. After annealing, an Ir1–xCoxO2 substitutional solid solution phase with rutile crystal structure was achieved for a wide Co-doping range 0 ≤ x ≤ 0.6. Starkly departing from the highly insulating behavior of CoO and Co3O4, the electrical resistivity at room temperature of our films is only slightly higher than that of IrO2. Likewise, our work shows that the magnetic response of the doped films is very similar to that of the paramagnetic parent IrO2. Neither ferromagnetism nor enhanced paramagnetism is observed. XAS spectra indicate a Co3+ oxidation state and, correspondingly, an oxidation state of ∼5+ for Ir ions in the polycrystalline Ir0.6Co0.4O2 film. By application of sum rules, a 13 % increase in the spin–orbit coupling is found despite the lattice shrinkage causes a detrimental bandwidth broadening.
Idioma: Inglés
DOI: 10.1016/j.jallcom.2023.171975
Año: 2023
Publicado en: JOURNAL OF ALLOYS AND COMPOUNDS 968 (2023), 171975 [7 pp.]
ISSN: 0925-8388

Factor impacto JCR: 5.8 (2023)
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 109 / 439 = 0.248 (2023) - Q1 - T1
Categ. JCR: METALLURGY & METALLURGICAL ENGINEERING rank: 8 / 90 = 0.089 (2023) - Q1 - T1
Categ. JCR: CHEMISTRY, PHYSICAL rank: 51 / 178 = 0.287 (2023) - Q2 - T1

Factor impacto CITESCORE: 11.1 - Metals and Alloys (Q1) - Materials Chemistry (Q1) - Mechanics of Materials (Q1) - Mechanical Engineering (Q1)

Factor impacto SCIMAGO: 1.103 - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Mechanics of Materials (Q1) - Mechanical Engineering (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E12-23R-RASMIA
Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2020-115159GB-I00/AEI/10.13039/501100011033
Financiación: info:eu-repo/grantAgreement/EC/H2020/101007825/EU/ULtra ThIn MAgneto Thermal sEnsor-Ing/ULTIMATE-I
Financiación: info:eu-repo/grantAgreement/EC/H2020/730872/EU/Convenient Access to Light Sources Open to Innovation, Science and to the World/CALIPSOplus
Financiación: info:eu-repo/grantAgreement/EC/H2020/872631 /EU/Memristive and multiferroic materials for emergent logic units in nanoelectronics/MELON
Tipo y forma: Article (Published version)
Área (Departamento): Área Cienc.Mater. Ingen.Metal. (Dpto. Ciencia Tecnol.Mater.Fl.)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)


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Exportado de SIDERAL (2024-11-22-11:58:29)


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Este artículo se encuentra en las siguientes colecciones:
Articles > Artículos por área > Ciencia de los Materiales e Ingeniería Metalúrgica
Articles > Artículos por área > Física de la Materia Condensada



 Record created 2023-10-27, last modified 2024-11-25


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