Unravelling the role of triisopropylphosphane telluride in Ag(I) complexes

Pérez-Sánchez, Juan Carlos ; Ceamanos, Carmen ; Pérez Herrera, Raquel ; Gimeno, M. Concepción

Resumen: The coordination chemistry of chalcogenide ligands has always attracted significant interest in the field of inorganic chemistry, especially for soft metals such as those of group 11. Despite the scarcity of research on phosphane tellurides, we report on the synthesis and characterisation of five novel silver complexes containing the phosphane telluride ligand, TeP(iPr)3, along with other ancillary ligands such as mono or diphosphanes. Spectroscopic studies were performed to investigate the behaviour of these complexes, including their redox properties, as demonstrated by the 1,1′-diphenylphosphaneferrocene (dppf) silver derivatives. Additionally, these complexes showcase remarkable rapid interchange equilibrium, revealing silver species with distinctive Ag2Te2 cores and a combination of bridging and terminal TeP(iPr)3 ligands. A promising avenue for further investigation and potential applications emerges.

Idioma: Inglés

DOI: 10.1039/d3qi01485a

Año: 2023

Publicado en: Inorganic Chemistry Frontiers 22 (2023), 6519-6525
ISSN: 2052-1545

Factor impacto JCR: 6.1 (2023)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 3 / 44 = 0.068 (2023) - Q1 - T1

Factor impacto SCIMAGO: 1.255 - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888
Financiación: info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00

Tipo y forma: Artículo (Versión definitiva)