Unravelling the role of triisopropylphosphane telluride in Ag(I) complexes
Pérez-Sánchez, Juan Carlos ; Ceamanos, Carmen ; Pérez Herrera, Raquel ; Gimeno, M. Concepción
Resumen: The coordination chemistry of chalcogenide ligands has always attracted significant interest in the field of inorganic chemistry, especially for soft metals such as those of group 11. Despite the scarcity of research on phosphane tellurides, we report on the synthesis and characterisation of five novel silver complexes containing the phosphane telluride ligand, TeP(iPr)3, along with other ancillary ligands such as mono or diphosphanes. Spectroscopic studies were performed to investigate the behaviour of these complexes, including their redox properties, as demonstrated by the 1,1′-diphenylphosphaneferrocene (dppf) silver derivatives. Additionally, these complexes showcase remarkable rapid interchange equilibrium, revealing silver species with distinctive Ag2Te2 cores and a combination of bridging and terminal TeP(iPr)3 ligands. A promising avenue for further investigation and potential applications emerges.
Idioma: Inglés
DOI: 10.1039/d3qi01485a
Año: 2023
Publicado en: Inorganic Chemistry Frontiers 22 (2023), 6519-6525
ISSN: 2052-1545
Factor impacto JCR: 6.1 (2023)
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 3 / 44 = 0.068 (2023) - Q1 - T1
Factor impacto CITESCORE: 10.4 - Inorganic Chemistry (Q1)
Factor impacto SCIMAGO: 1.255 - Inorganic Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888
Financiación: info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes.
Exportado de SIDERAL (2024-11-22-12:12:14)
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Idioma: Inglés
DOI: 10.1039/d3qi01485a
Año: 2023
Publicado en: Inorganic Chemistry Frontiers 22 (2023), 6519-6525
ISSN: 2052-1545
Factor impacto JCR: 6.1 (2023)
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 3 / 44 = 0.068 (2023) - Q1 - T1
Factor impacto CITESCORE: 10.4 - Inorganic Chemistry (Q1)
Factor impacto SCIMAGO: 1.255 - Inorganic Chemistry (Q1)
Financiación: info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21
Financiación: info:eu-repo/grantAgreement/ES/DGA/E07-23R
Financiación: info:eu-repo/grantAgreement/ES/MCIN/AEI/PID2020-117455GB-I00
Financiación: info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888
Financiación: info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00
Tipo y forma: Article (Published version)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. Exportado de SIDERAL (2024-11-22-12:12:14)
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Record created 2023-10-27, last modified 2024-11-25