000128041 001__ 128041 000128041 005__ 20240720100904.0 000128041 0247_ $$2doi$$a10.1039/d3qi01485a 000128041 0248_ $$2sideral$$a135134 000128041 037__ $$aART-2023-135134 000128041 041__ $$aeng 000128041 100__ $$0(orcid)0000-0002-5298-8351$$aPérez-Sánchez, Juan Carlos 000128041 245__ $$aUnravelling the role of triisopropylphosphane telluride in Ag(I) complexes 000128041 260__ $$c2023 000128041 5060_ $$aAccess copy available to the general public$$fUnrestricted 000128041 5203_ $$aThe coordination chemistry of chalcogenide ligands has always attracted significant interest in the field of inorganic chemistry, especially for soft metals such as those of group 11. Despite the scarcity of research on phosphane tellurides, we report on the synthesis and characterisation of five novel silver complexes containing the phosphane telluride ligand, TeP(iPr)3, along with other ancillary ligands such as mono or diphosphanes. Spectroscopic studies were performed to investigate the behaviour of these complexes, including their redox properties, as demonstrated by the 1,1′-diphenylphosphaneferrocene (dppf) silver derivatives. Additionally, these complexes showcase remarkable rapid interchange equilibrium, revealing silver species with distinctive Ag2Te2 cores and a combination of bridging and terminal TeP(iPr)3 ligands. A promising avenue for further investigation and potential applications emerges. 000128041 536__ $$9info:eu-repo/grantAgreement/ES/AEI/PID2019-104379RB-C21$$9info:eu-repo/grantAgreement/ES/DGA/E07-23R$$9info:eu-repo/grantAgreement/ES/MCIN/AEI/PID2020-117455GB-I00$$9info:eu-repo/grantAgreement/ES/MCIU/FPU21/01888$$9info:eu-repo/grantAgreement/ES/MICINN AEI/PID2022-136861NB-I00 000128041 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/ 000128041 590__ $$a6.1$$b2023 000128041 592__ $$a1.255$$b2023 000128041 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b3 / 44 = 0.068$$c2023$$dQ1$$eT1 000128041 593__ $$aInorganic Chemistry$$c2023$$dQ1 000128041 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000128041 700__ $$aCeamanos, Carmen 000128041 700__ $$0(orcid)0000-0002-5244-9569$$aPérez Herrera, Raquel 000128041 700__ $$0(orcid)0000-0003-0553-0695$$aGimeno, M. Concepción 000128041 773__ $$g22 (2023), 6519-6525$$pInorg. chem. front$$tInorganic Chemistry Frontiers$$x2052-1545 000128041 8564_ $$s845537$$uhttps://zaguan.unizar.es/record/128041/files/texto_completo.pdf$$yVersión publicada 000128041 8564_ $$s2753943$$uhttps://zaguan.unizar.es/record/128041/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000128041 909CO $$ooai:zaguan.unizar.es:128041$$particulos$$pdriver 000128041 951__ $$a2024-07-19-18:53:48 000128041 980__ $$aARTICLE