000129847 001__ 129847
000129847 005__ 20240112163659.0
000129847 0247_ $$2doi$$a10.1002/adfm.201801695
000129847 0248_ $$2sideral$$a107599
000129847 037__ $$aART-2018-107599
000129847 041__ $$aeng
000129847 100__ $$0(orcid)0000-0002-8424-9780$$aUrtizberea, A.
000129847 245__ $$aA Porphyrin Spin Qubit and Its 2D Framework Nanosheets
000129847 260__ $$c2018
000129847 5060_ $$aAccess copy available to the general public$$fUnrestricted
000129847 5203_ $$aMolecular spin qubits have been shown to reach sufficiently long quantum coherence times to envision their use as hardware in quantum processors. These will however require their implementation in hybrid solid-state devices for which the controlled localization and homogeneous orientation of the molecular qubits will be necessary. An alternative to isolated molecules that can ensure these key aspects is 2D framework in which the qubit would act as node. In this work, it is demonstrated that the isolated metalloporphyrin [Cu(H4TCPP)] molecule is a potential spin qubit, and maintains similar quantum coherence as node in a 2D [{CuTCPP}Zn2(H2O)2] metal–organic framework. Mono- and multilayer deposits of nanosheets of a similar 2D framework are then successfully formed following a modular method based on Langmuir–Schaefer conditions. The orientation of the {CuTCPP} qubit nodes in these nanosheets is homogeneous parallel to the substrate. These nanosheets are also formed with a control over the qubit concentration, i.e., by dilution with the unmetallated porphyrin. Eventually, 2D nanosheets are formed in situ directly on a substrate, through a simple protocol devised to reproduce the Langmuir–Schaefer conditions locally. Altogether these studies show that 2D spin qubit frameworks are ideal components to develop a hybrid quantum computing architecture.
000129847 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E31-17R$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-64486-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2014-53961-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2015-70868-ERC$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2016-78257-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2017-86826-R
000129847 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000129847 590__ $$a15.621$$b2018
000129847 591__ $$aCHEMISTRY, PHYSICAL$$b5 / 147 = 0.034$$c2018$$dQ1$$eT1
000129847 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b15 / 293 = 0.051$$c2018$$dQ1$$eT1
000129847 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b7 / 94 = 0.074$$c2018$$dQ1$$eT1
000129847 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b11 / 172 = 0.064$$c2018$$dQ1$$eT1
000129847 591__ $$aPHYSICS, CONDENSED MATTER$$b5 / 68 = 0.074$$c2018$$dQ1$$eT1
000129847 591__ $$aPHYSICS, APPLIED$$b6 / 148 = 0.041$$c2018$$dQ1$$eT1
000129847 592__ $$a5.646$$b2018
000129847 593__ $$aBiomaterials$$c2018$$dQ1
000129847 593__ $$aCondensed Matter Physics$$c2018$$dQ1
000129847 593__ $$aNanoscience and Nanotechnology$$c2018$$dQ1
000129847 593__ $$aElectronic, Optical and Magnetic Materials$$c2018$$dQ1
000129847 593__ $$aElectrochemistry$$c2018$$dQ1
000129847 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000129847 700__ $$0(orcid)0000-0003-2553-0633$$aNatividad, E.$$uUniversidad de Zaragoza
000129847 700__ $$0(orcid)0000-0003-3449-4929$$aAlonso, P.J.$$uUniversidad de Zaragoza
000129847 700__ $$0(orcid)0000-0003-3691-3437$$aAndrés, M.A.$$uUniversidad de Zaragoza
000129847 700__ $$0(orcid)0000-0002-3492-6456$$aGascón, I.$$uUniversidad de Zaragoza
000129847 700__ $$aGoldmann, M.
000129847 700__ $$0(orcid)0000-0003-2095-5843$$aRoubeau, O.$$uUniversidad de Zaragoza
000129847 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000129847 7102_ $$15001$$2065$$aUniversidad de Zaragoza$$bDpto. Ciencia Tecnol.Mater.Fl.$$cÁrea Cienc.Mater. Ingen.Metal.
000129847 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000129847 773__ $$g28, 31 (2018), 1801695 [15 pp]$$pAdv. funct. mater.$$tAdvanced Functional Materials$$x1616-301X
000129847 8564_ $$s4883293$$uhttps://zaguan.unizar.es/record/129847/files/texto_completo.pdf$$yPostprint
000129847 8564_ $$s1280819$$uhttps://zaguan.unizar.es/record/129847/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000129847 909CO $$ooai:zaguan.unizar.es:129847$$particulos$$pdriver
000129847 951__ $$a2024-01-12-14:08:04
000129847 980__ $$aARTICLE