The hydration behavior of D-glucose in the choline chloride: Urea:water mixtures
Díaz-Ruiz, Raquel ; Bergua, Fernando ; Muñoz-Embid, José (Universidad de Zaragoza) ; Lafuente, Carlos (Universidad de Zaragoza) ; Artal, Manuela (Universidad de Zaragoza)
Resumen: The hydration behavior of D-glucose in aqueous solutions containing a deep eutectic solvent (DES) was studied in the temperature range: T = (293.15–313.15) K. For that, several volumetric, acoustic and viscometric properties were measured and calculated. The choline chloride + urea (1, 2, molar ratio) eutectic mixture was chosen as co-solvent. The Hepler parameter and the viscosity B-coefficient showed that D-glucose in DES aqueous mixtures is a structure-making agent. Both the molar properties and the transfer properties suggested a strong solute-solvent interaction with predominance of the hydrophilic -hydrophilic contribution. Lastly, the calculated viscous flow activation parameters demonstrated high stability of the hydration structure.
Idioma: Inglés
DOI: 10.1016/j.molliq.2020.113649
Año: 2020
Publicado en: Journal of Molecular Liquids 314 (2020), 113649 1-8
ISSN: 0167-7322
Factor impacto JCR: 6.165 (2020)
Categ. JCR: PHYSICS, ATOMIC, MOLECULAR & CHEMICAL rank: 4 / 37 = 0.108 (2020) - Q1 - T1
Categ. JCR: CHEMISTRY, PHYSICAL rank: 43 / 162 = 0.265 (2020) - Q2 - T1
Factor impacto SCIMAGO: 0.929 - Atomic and Molecular Physics, and Optics (Q1) - Condensed Matter Physics (Q1) - Spectroscopy (Q1) - Materials Chemistry (Q1) - Physical and Theoretical Chemistry (Q1) - Electronic, Optical and Magnetic Materials (Q1)
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Física (Dpto. Química Física)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
Exportado de SIDERAL (2024-02-01-14:38:22)
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Idioma: Inglés
DOI: 10.1016/j.molliq.2020.113649
Año: 2020
Publicado en: Journal of Molecular Liquids 314 (2020), 113649 1-8
ISSN: 0167-7322
Factor impacto JCR: 6.165 (2020)
Categ. JCR: PHYSICS, ATOMIC, MOLECULAR & CHEMICAL rank: 4 / 37 = 0.108 (2020) - Q1 - T1
Categ. JCR: CHEMISTRY, PHYSICAL rank: 43 / 162 = 0.265 (2020) - Q2 - T1
Factor impacto SCIMAGO: 0.929 - Atomic and Molecular Physics, and Optics (Q1) - Condensed Matter Physics (Q1) - Spectroscopy (Q1) - Materials Chemistry (Q1) - Physical and Theoretical Chemistry (Q1) - Electronic, Optical and Magnetic Materials (Q1)
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Química Física (Dpto. Química Física)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2024-02-01-14:38:22)
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Record created 2024-02-01, last modified 2024-02-01