Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
Hidalgo, Nereida ; Moreno, Juan José ; García-Rubio, Inés (Universidad de Zaragoza) ; Campos, Jesús
Resumen: The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity of their metalloradical species is though remarkable, albeit yet poorly understood and with limited mechanistic investigations available. In this work we report the synthesis and characterization of two mononuclear IrII species, including the first dinitrogen adduct. These compounds activate dihydrogen at a dissimilar rate, in the latter case several orders of magnitude faster than its IrI precursor. A combined experimental/computational investigation to ascertain the mechanism of this transformation in IrII compounds is reported.
Idioma: Inglés
DOI: 10.1002/anie.202206831
Año: 2022
Publicado en: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61, 35 (2022), e202206831 [7 pp.]
ISSN: 1433-7851
Factor impacto JCR: 16.6 (2022)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 13 / 178 = 0.073 (2022) - Q1 - T1
Factor impacto CITESCORE: 26.3 - Chemistry (Q1) - Chemical Engineering (Q1)
Factor impacto SCIMAGO: 5.573 - Chemistry (miscellaneous) (Q1) - Catalysis (Q1)
Financiación: info:eu-repo/grantAgreement/EC/H2020/756575/EU/Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts/CoopCat
Financiación: info:eu-repo/grantAgreement/ES/MCIU/PID2019-110856GA-I00
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
Exportado de SIDERAL (2024-03-18-14:31:06)
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Idioma: Inglés
DOI: 10.1002/anie.202206831
Año: 2022
Publicado en: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 61, 35 (2022), e202206831 [7 pp.]
ISSN: 1433-7851
Factor impacto JCR: 16.6 (2022)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 13 / 178 = 0.073 (2022) - Q1 - T1
Factor impacto CITESCORE: 26.3 - Chemistry (Q1) - Chemical Engineering (Q1)
Factor impacto SCIMAGO: 5.573 - Chemistry (miscellaneous) (Q1) - Catalysis (Q1)
Financiación: info:eu-repo/grantAgreement/EC/H2020/756575/EU/Cooperative Catalysis: Using Interdisciplinary Chemical Systems to Develop New Cooperative Catalysts/CoopCat
Financiación: info:eu-repo/grantAgreement/ES/MCIU/PID2019-110856GA-I00
Tipo y forma: Article (Published version)
Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2024-03-18-14:31:06)
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Articles > Artículos por área > Física de la Materia Condensada
Record created 2024-02-12, last modified 2024-03-19