Tailored design of a water-based nanoreactor technology for producing processable Sub-40 Nm 3D COF nanoparticles at atmospheric conditions

Llauradó-Capdevila, Gemma ; Veciana, Andrea ; Guarducci, María Aurora ; Mayoral, Álvaro (Universidad de Zaragoza) ; Pons, Ramon ; Hertle, Lukas ; Ye, Hao ; Mao, Minmin ; Sevim, Semih ; Rodríguez-San-Miguel, David ; Sorrenti, Alessandro ; Jang, Bumjin ; Wang, Zuobin ; Chen, Xiang-Zhong ; Nelson, Bradley J. ; Matheu, Roc ; Franco, Carlos ; Pané, Salvador ; Puigmartí-Luis, Josep

Resumen: Covalent organic frameworks (COFs) are crystalline materials with intrinsic porosity that offer a wide range of potential applications spanning diverse fields. Yet, the main goal in the COF research area is to achieve the most stable thermodynamic product while simultaneously targeting the desired size and structure crucial for enabling specific functions. While significant progress is made in the synthesis and processing of 2D COFs, the development of processable 3D COF nanocrystals remains challenging. Here, a water‐based nanoreactor technology for producing processable sub‐40 nm 3D COF nanoparticles at ambient conditions is presented. Significantly, this technology not only improves the processability of the synthesized 3D COF, but also unveils exciting possibilities for their utilization in previously unexplored domains, such as nano/microrobotics and biomedicine, which are limited by larger crystallites.

Idioma: Inglés

DOI: 10.1002/adma.202306345

Año: 2023

Publicado en: Advanced materials 36, 14 (2023), 2306345 [9 pp.]
ISSN: 0935-9648

Factor impacto JCR: 27.4 (2023)

Categ. JCR: CHEMISTRY, PHYSICAL rank: 4 / 178 = 0.022 (2023) - Q1 - T1
Categ. JCR: MATERIALS SCIENCE, MULTIDISCIPLINARY rank: 11 / 439 = 0.025 (2023) - Q1 - T1
Categ. JCR: NANOSCIENCE & NANOTECHNOLOGY rank: 4 / 141 = 0.028 (2023) - Q1 - T1
Categ. JCR: PHYSICS, CONDENSED MATTER rank: 3 / 79 = 0.038 (2023) - Q1 - T1
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 5 / 231 = 0.022 (2023) - Q1 - T1
Categ. JCR: PHYSICS, APPLIED rank: 6 / 179 = 0.034 (2023) - Q1 - T1

Factor impacto CITESCORE: 43.0 - Mechanical Engineering (Q1) - Materials Science (all) (Q1) - Mechanics of Materials (Q1)

Factor impacto SCIMAGO: 9.191 - Materials Science (miscellaneous) (Q1) - Nanoscience and Nanotechnology (Q1) - Mechanics of Materials (Q1) - Mechanical Engineering (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E13-20R
Financiación: info:eu-repo/grantAgreement/EC/HORIZON EUROPE/101047081/EU/Magnetoelectric 3D printing technology - the revolution of actuatable composites/EVA
Financiación: info:eu-repo/grantAgreement/ES/MICINN-AEI/PID2021-1248480OB-I00
Financiación: info:eu-repo/grantAgreement/ES/MICINN/AEI/116612RB-C33
Financiación: info:eu-repo/grantAgreement/ES/MICINN/CEX2021-001202-M
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I
Financiación: info:eu-repo/grantAgreement/ES/MICINN/RYC2021-031578-I

Tipo y forma: Article (Published version)

Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)