Design of glycerol-based solvents for the immobilization of palladium nanocatalysts: a hydrogenation study

Leal-Duaso, Alejandro ; Favier, Isabelle ; Pla, Daniel ; Pires, Elísabet (Universidad de Zaragoza) ; Gómez, Montserrat

Resumen: Twenty-one green solvents, including glycerol-derived ethers, and their eutectic mixtures with two renewable ammonium salts, were used for the straightforward synthesis, stabilization, and immobilization of palladium nanoparticles (Pd NPs). The nature of the solvent allows tuning of the characteristics and properties of resulting catalytic systems in terms of particle size and morphology, stability, reactivity, and recoverability. Pd NPs immobilized in glycerol-based solvents were applied in the catalytic hydrogenation of alkenes, alkynes, and carbonyl compounds, as well as in the selective semihydrogenation of alkynes to alkenes. The optimal experimental parameters and the influence on the reactivity of the physicochemical properties of solvent, mainly the viscosity, were studied. Moreover, the most active and recoverable catalytic system, Pd NPs/N00Cl-100, was fully characterized both in the liquid phase and in the solid state, and its deactivation upon recovery was analyzed.

Idioma: Inglés

DOI: 10.1021/acssuschemeng.1c01694

Año: 2021

Publicado en: ACS Sustainable Chemistry and Engineering 9, 19 (2021), 6875-6885
ISSN: 2168-0485

Factor impacto JCR: 9.224 (2021)

Categ. JCR: ENGINEERING, CHEMICAL rank: 13 / 142 = 0.092 (2021) - Q1 - T1
Categ. JCR: GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY rank: 10 / 47 = 0.213 (2021) - Q1 - T1
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 29 / 179 = 0.162 (2021) - Q1 - T1

Factor impacto CITESCORE: 14.5 - Environmental Science (Q1) - Chemical Engineering (Q1) - Energy (Q1)

Factor impacto SCIMAGO: 1.743 - Chemical Engineering (miscellaneous) (Q1) - Renewable Energy, Sustainability and the Environment (Q1) - Chemistry (miscellaneous) (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-ERDF/E37-20R
Financiación: info:eu-repo/grantAgreement/ES/MEC/FPU14-04338
Financiación: info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-I00

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Química Orgánica (Dpto. Química Orgánica)